Evidence map›Paper›PMID 34367720›Full record

ArticleACS catalysis2020

Mechanistic Study of Isotactic Poly(propylene oxide) Synthesis using a Tethered Bimetallic Chromium Salen Catalyst.

Bryce M Lipinski, Katherine L Walker, Naomi E Clayman, Lilliana S Morris, Timothy M E Jugovic, Allison G Roessler, Yutan D Y L Getzler, Samantha N MacMillan, Richard N Zare, Paul M Zimmerman and 2 more

Abstract read
In one paragraph

Article in ACS catalysis, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Bryce M LipinskiDepartment of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853-1301, United States.ORCID 0000-0001-7769-4678
Katherine L Walker *Department of Chemistry, Stanford University, Stanford, California 94305-5080, United States.ORCID 0000-0002-7924-8185
Naomi E Clayman *Department of Chemistry, Stanford University, Stanford, California 94305-5080, United States.ORCID 0000-0002-4894-2174
Lilliana S Morris *Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853-1301, United States.ORCID 0000-0002-9184-7201
Timothy M E JugovicDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1382, United States.
Allison G RoesslerDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1382, United States.ORCID 0000-0002-1368-5374
Yutan D Y L GetzlerDepartment of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853-1301, United States.ORCID 0000-0001-5219-911X
Samantha N MacMillanDepartment of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853-1301, United States.ORCID 0000-0001-6516-1823
Richard N ZareDepartment of Chemistry, Stanford University, Stanford, California 94305-5080, United States.ORCID 0000-0001-5266-4253
Paul M ZimmermanDepartment of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1382, United States.ORCID 0000-0002-7444-1314
Robert M WaymouthDepartment of Chemistry, Stanford University, Stanford, California 94305-5080, United States.ORCID 0000-0001-9862-9509
Geoffrey W CoatesDepartment of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853-1301, United States.ORCID 0000-0002-3400-2552

Funding

Mechanism-Guided Catalyst Development through Reaction Discovery Simulation - Equipment SupplementR35GM128830 · NIGMS · UNIVERSITY OF MICHIGAN AT ANN ARBOR · PI ZIMMERMAN, PAUL · 2018 to 2022
$1.9M
NIGMS NIH HHS R35 GM128830
6 · The paper itself

Abstract

Initial catalyst dormancy has been mitigated for the enantioselective polymerization of propylene oxide using a tethered bimetallic chromium(III) salen complex. A detailed mechanistic study provided insight into the species responsible for this induction period and guided efforts to remove them. High-resolution electrospray ionization-mass spectrometry and density functional theory computations revealed that a

Indexed as

arrest statebimetallic catalysisenantioselectiveisotactic polyethersmechanismpolyols

Identifiers

PMID34367720
PMCPMC8345319

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.