ArticleMolecules (Basel, Switzerland)2021
A Critical Look at Linus Pauling's Influence on the Understanding of Chemical Bonding.
Article in Molecules (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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3 citing papers in PubMed, 18 citations in OpenAlex.
- Silylene-Stabilized Neutral Dibora-Aromatics with a B═B Bond.Journal of the American Chemical Society · 2024Article
- Unusual Water Oxidation Mechanism via a Redox-Active Copper Polypyridyl Complex.Inorganic chemistry · 2023Article
- The stability of covalent dative bond significantly increases with increasing solvent polarity.Nature communications · 2022Article
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2 authors at 1 institution in 2 countries.
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Abstract
The influence of Linus Pauling on the understanding of chemical bonding is critically examined. Pauling deserves credit for presenting a connection between the quantum theoretical description of chemical bonding and Gilbert Lewis's classical bonding model of localized electron pair bonds for a wide range of chemistry. Using the concept of resonance that he introduced, he was able to present a consistent description of chemical bonding for molecules, metals, and ionic crystals which was used by many chemists and subsequently found its way into chemistry textbooks. However, his one-sided restriction to the valence bond method and his rejection of the molecular orbital approach hindered further development of chemical bonding theory for a while and his close association of the heuristic Lewis binding model with the quantum chemical VB approach led to misleading ideas until today.
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