ArticleOrganic chemistry frontiers : an international journal of organic chemistry2021
Exploiting coordination geometry to tune the dimensions and processability of metallosupramolecular polymers.
Article in Organic chemistry frontiers : an international journal of organic chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Counterion Dynamics in Chiral Supramolecular Polymerization.Angewandte Chemie (International ed. in English) · 2026Article
- Photo- and thermo-responsive complementary metal coordination for the construction of supramolecular polymers.Chemical science · 2026Article
- Interfacing Flexible Design and Social Self-Sorting Enables Comprehensive Control over Photophysical and Self-Assembly Properties of Supramolecular Polymers.Journal of the American Chemical Society · 2025Article
- Controlling Molecular Packing in Aqueous Metallosupramolecular Self-assembly by Ligand Geometry.Precision chemistry · 2023Article
- Multi-chiral materials comprising metallosupramolecular and covalent helical polymers containing five axial motifs within a helix.Nature communications · 2023Article
- Bioinspired crowding directs supramolecular polymerisation.Nature communications · 2023Article
- Luminescence and Length Control in Nonchelated dAngewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
6 authors.
Funding
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Abstract
Achieving precise control over the morphology, dimensions and processability of functional materials is a key but challenging requirement for the fabrication of smart devices. To address this issue, we herein compare the self-assembly behavior of two new Pt(ii) complexes that differ in the molecular and coordination geometry through implementation of either a monodentate (pyridine) or bidentate (bipyridine) ligand. The molecular preorganization of the bipyridine-based complex enables effective self-assembly in solution involving Pt⋯Pt interactions, while preserving aggregate solubility. On the other hand, increased steric effects of the linear bispyridine-based complex hinder an effective preorganization leading to poorly solvated aggregates when a critical concentration is exceeded.
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Registered trials
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