ReviewChemical Society reviews2021
Evolution towards green radical generation in total synthesis.
Review in Chemical Society reviews, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
15 citing papers in PubMed.
- Photofracking-Assisted Enhancement of Solid-State Photochemical Reactivity: α-Azido-5-phenyl-2,4-dienoate Derivatives.Journal of the American Chemical Society · 2026Article
- Review
- Harnessing redox properties of organic persistent radicals in SET-induced transformations.Beilstein journal of organic chemistry · 2026Review
- Bimolecular Homolytic Substitution (SACS central science · 2025Review
- Nitrogen-Centered Organic Persistent Radicals Catalyze Redox-Neutral C─C Bond Forming Reactions.Angewandte Chemie (International ed. in English) · 2025Article
- Catalytic 1,2-Radical Acyloxy Migration: A Strategy to Access Novel Chemical Space and Reaction Profiles.Accounts of chemical research · 2025Article
- Electrochemically Induced, Metal Free Synthesis of 2-substituted chroman-4-ones.ChemistryOpen · 2025Article
- Rational design of super reductive EDA photocatalyst for challenging reactions: a theoretical and experimental study.RSC advances · 2024Article
- Mechanisms for radical reactions initiating fromBeilstein journal of organic chemistry · 2024Article
- Leveraging the Persistent Radical Effect in the Synthesis of trans-2,3-Diaryl Dihydrobenzofurans.Angewandte Chemie (International ed. in English) · 2023Article
- Catalytic photochemical enantioselective α-alkylation with pyridinium salts.Chemical science · 2023Article
- Combining the best of both worlds: radical-based divergent total synthesis.Beilstein journal of organic chemistry · 2023Review
- Direct C-H Trifluoromethylation of (Hetero)Arenes in Water Enabled by Organic Photoredox-Active Amphiphilic Nanoparticles.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Visible-light-promoted and chlorophyll-catalyzed aerobic desulfurization of thioamides to amides.RSC advances · 2022Article
- Photoinduced metal-free borylation of aryl halides catalysed by anChemical science · 2022Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
Abstract
The use of radicals as intermediates in total synthesis has evolved since their initial use in the latter half of the twentieth century. Radical generation from metal hydride methodologies has shifted to "greener" techniques including catalytic metal-mediated systems, electrochemical and photoredox-mediated processes. This review will focus on these classical and contemporary methods for radical generation and their applications in recent total syntheses.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.