ArticleChemical science2021
Stereoselective tandem iridium-catalyzed alkene isomerization-cope rearrangement of ω-diene epoxides: efficient access to acyclic 1,6-dicarbonyl compounds.
Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Methods and applications for epoxide C-C bond cleavage reactions.Nature reviews. Chemistry · 2026Review
- B(CChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Preparation of Distant Quaternary Carbon Stereocenters by Double Selective Ring-Opening of 1,1-Biscyclopropyl Methanol Derivatives.Angewandte Chemie (International ed. in English) · 2022Article
- Chemical kinetics and promoted Co-immobilization for efficient catalytic carbonylation of ethylene oxide into methyl 3-hydroxypropionate.Frontiers in chemistry · 2022Article
- Stereodivergent Access to Trisubstituted Alkenylboronate Esters through Alkene Isomerization.Organic letters · 2021Article
- Alkene Isomerization Revitalizes the Coates-Claisen Rearrangement.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
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Authors and funding
3 authors.
Funding
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Abstract
The Cope rearrangement of 2,3-divinyloxiranes, a rare example of epoxide C-C bond cleavage, results in 4,5-dihydrooxepines which are amenable to hydrolysis, furnishing 1,6-dicarbonyl compounds containing two contiguous stereocenters at the 3- and 4-positions. We employ an Ir-based alkene isomerization catalyst to form the reactive 2,3-divinyloxirane
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Registered trials
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