Evidence map›Paper›PMID 34344963›Full record

ArticleScientific reports2021

Exploring tailor-made Brønsted acid sites in mesopores of tin oxide catalyst for β-alkoxy alcohol and amino alcohol syntheses.

Pandian Manjunathan, Varsha Prasanna, Ganapati V Shanbhag

Abstract read
In one paragraph

Article in Scientific reports, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Pandian ManjunathanMaterials Science and Catalysis Division, Poornaprajna Institute of Scientific Research (PPISR), Bidalur, Devanahalli, Bengaluru, Karnataka, 562164, India. pandianmanjunathan89@gmail.com.
Varsha PrasannaMaterials Science and Catalysis Division, Poornaprajna Institute of Scientific Research (PPISR), Bidalur, Devanahalli, Bengaluru, Karnataka, 562164, India.
Ganapati V ShanbhagMaterials Science and Catalysis Division, Poornaprajna Institute of Scientific Research (PPISR), Bidalur, Devanahalli, Bengaluru, Karnataka, 562164, India. shanbhag@poornaprajna.org.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The generation of Brønsted (Sn-OH) and Lewis (coordinatively unsaturated metal centers) acidic sites on the solid surface is a prime demand for catalytic applications. Mesoporous materials are widely employed as catalysts and supports owing to their different nature of acidic sites. Nevertheless, the procedure adopted to generate acid functionalities in these materials involves tedious steps. Herein, we report the tunable acidic sites containing Brønsted sites with relatively varied acid strength in tin oxide by employing soft template followed by simple thermal treatment at various temperatures. The readily accessible active sites, specifically Brønsted acidic sites distributed throughout the tin oxide framework as well as mesoporosity endow them to perform with exceptionally high efficiency for epoxide ring opening reactions with excellent reusability. These features promoted them to surpass stannosilicate catalysts for the epoxide ring opening reactions with alcohol as a nucleophile and the study was extended to aminolysis of epoxide with the amine. The existence of relatively greater acid strength and numbers in T-SnO

Identifiers

PMID34344963
PMCPMC8333069

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.