ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2021
Photocleavable Regenerative Network Materials with Exceptional and Repeatable Viscoelastic Manipulability.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
3 citing papers in PubMed, 20 citations in OpenAlex.
- Synergetic binary organocatalyzed ring opening polymerization for the precision synthesis of polysiloxanes.Communications chemistry · 2024Article
- Review
- Photocleavable Regenerative Network Materials with Exceptional and Repeatable Viscoelastic Manipulability.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2021Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors at 4 institutions in 2 countries.
Funding
Abstract
The development of solventless system for modulating properties of network materials is imperative for the next generation sustainable technology. Utilization of photostimulation is important owing to its spatial and temporal locality, yet designing photoresponsive network materials exhibiting repeatable and dramatic change in their properties remains a challenge. Here, the authors report a photocleavable regenerative network (PRN) linked with photoresponsive hexaarylbiimidazoles (HABIs) synthesized from narrow dispersity star-shaped poly(dimethylsiloxane)s (PDMSs) having 2,4,5-triphenylimidazole end groups. The use of urea anion as a catalyst for ring opening polymerization (ROP) of cyclic siloxane initiated from silanols enables control of molecular weight and dispersity. The rheological measurements for the synthesized PRNs exhibit drastic changes in storage and loss moduli (G' and G″) upon photoirradiation in the solid state (G' > G″). This photocontrolled change in viscoelasticity with retaining solidity enables application of PRNs as a remotely-controlled photo-melt adhesive and photo-scissible string. The developed PRNs will enable a wide variety of applications such as industrially important next-generation sustainable adhesive, sealant, and reversibly-deformable 3D printing materials with their spatially and temporally local manipulability, solventless handleability, and excellent reversibility.
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What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.