Evidence map›Paper›PMID 34330828›Full record

ArticleProceedings of the National Academy of Sciences of the United States of America2021

Glasses denser than the supercooled liquid.

Yi Jin, Aixi Zhang, Sarah E Wolf, Shivajee Govind, Alex R Moore, Mikhail Zhernenkov, Guillaume Freychet, Ahmad Arabi Shamsabadi, Zahra Fakhraai

Abstract read
In one paragraph

Article in Proceedings of the National Academy of Sciences of the United States of America, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Yi JinDepartment of Chemistry, University of Pennsylvania, Philadelphia, PA 19104.ORCID 0000-0002-5633-8305
Aixi ZhangDepartment of Chemistry, University of Pennsylvania, Philadelphia, PA 19104.ORCID 0000-0002-6214-7978
Sarah E WolfDepartment of Chemistry, University of Pennsylvania, Philadelphia, PA 19104.ORCID 0000-0001-7695-7923
Shivajee GovindDepartment of Chemistry, University of Pennsylvania, Philadelphia, PA 19104.ORCID 0000-0003-2356-4063
Alex R MooreDepartment of Chemical and Biomolecular Engineering, University of Pennsylvania, Philadelphia, PA 19104.
Mikhail ZhernenkovNational Synchrotron Light Source II (NSLS-II), Brookhaven National Laboratory, Upton, NY 11973.ORCID 0000-0003-3604-0672
Guillaume FreychetNational Synchrotron Light Source II (NSLS-II), Brookhaven National Laboratory, Upton, NY 11973.ORCID 0000-0001-8406-798X
Ahmad Arabi ShamsabadiDepartment of Chemistry, University of Pennsylvania, Philadelphia, PA 19104.
Zahra FakhraaiDepartment of Chemistry, University of Pennsylvania, Philadelphia, PA 19104; fakhraai@sas.upenn.edu.ORCID 0000-0002-0597-9882

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

When aged below the glass transition temperature, [Formula: see text], the density of a glass cannot exceed that of the metastable supercooled liquid (SCL) state, unless crystals are nucleated. The only exception is when another polyamorphic SCL state exists, with a density higher than that of the ordinary SCL. Experimentally, such polyamorphic states and their corresponding liquid-liquid phase transitions have only been observed in network-forming systems or those with polymorphic crystalline states. In otherwise simple liquids, such phase transitions have not been observed, either in aged or vapor-deposited stable glasses, even near the Kauzmann temperature. Here, we report that the density of thin vapor-deposited films of

Indexed as

liquid–liquid phase transitionmobile surface layerphysical vapor depositionstable glassthin-film mobility

Identifiers

PMID34330828
PMCPMC8346856

What OpenQuestion holds

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.