ArticleAngewandte Chemie (International ed. in English)2021
Chiral Distorted Hexa-peri-hexabenzocoronenes Bearing a Nonagon-Embedded Carbohelicene.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Twenty Years of Graphene: From Pristine to Chemically Engineered Nano-Sized Flakes.Journal of the American Chemical Society · 2024Review
- Curved Nanographenes as Stoppers in a [2]Rotaxane with Two-Photon Excited Emission.The Journal of organic chemistry · 2024Article
- Chalcogen-doped, (Chemical science · 2023Article
- Helical Bilayer Nanographenes: Impact of the Helicene Length on the Structural, Electrochemical, Photophysical, and Chiroptical Properties.Journal of the American Chemical Society · 2023Article
- BINOL-like atropisomeric chiral nanographene.Chemical science · 2023Article
- Helical Bilayer Nonbenzenoid Nanographene Bearing a [10]Helicene with Two Embedded Heptagons.Angewandte Chemie (International ed. in English) · 2023Article
- Atomically Precise Distorted Nanographenes: The Effect of Different Edge Functionalization on the Photophysical Properties down to the Femtosecond Scale.Materials (Basel, Switzerland) · 2023Article
- Construction of hexabenzocoronene-based chiral nanographenes.Beilstein journal of organic chemistry · 2023Review
- Chiral Distorted Hexa-peri-hexabenzocoronenes Bearing a Nonagon-Embedded Carbohelicene.Angewandte Chemie (International ed. in English) · 2021Article
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6 authors.
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Abstract
A new family of chiral saddle-helix hybrid nanographenes is reported. The first hexa-peri-hexabenzocoronene (HBC) analogues bearing a nine-membered carbocycle are presented. Furthermore, for the first time, π-extended carbo[n]helicenes containing a nine-membered ring as part of the helical moiety have been synthesized. The combination of a [5]helicene moiety and a nonagon ring in a single chiral motif induces a tremendous distortion from planarity into the nanographenic structures compared to other saddle-helix hybrids such as heptagon- and octagon-containing π-extended carbo[5]helicenes. In fact, the interplanar angle of the two terminal rings reaches the largest angle (134.8°) of a carbohelicene reported to date, thus being by far the most twisted helicene yet prepared. Photophysical properties evaluation showed improved absorption dissymmetry factors (|g
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