Evidence map›Paper›PMID 34324754›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021

Iron(II)-Catalyzed Aerobic Biomimetic Oxidation of N-Heterocycles.

Srimanta Manna, Wei-Jun Kong, Jan-E Bäckvall

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Selective Iron Catalyzed Synthesis of N-Alkylated Indolines and Indoles.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Article
  3. Iron(II)-Catalyzed Aerobic Biomimetic Oxidation of N-Heterocycles.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Srimanta MannaDepartment of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.ORCID http://orcid.org/0000-0002-3903-1256
Wei-Jun KongDepartment of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.ORCID http://orcid.org/0000-0003-2247-594X
Jan-E BäckvallDepartment of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.ORCID http://orcid.org/0000-0001-8462-4176

Funding

Vetenskapsrådet 2019-04042
6 · The paper itself

Abstract

Herein, an iron(II)-catalyzed biomimetic oxidation of N-heterocycles under aerobic conditions is described. The dehydrogenation process, involving several electron-transfer steps, is inspired by oxidations occurring in the respiratory chain. An environmentally friendly and inexpensive iron catalyst together with a hydroquinone/cobalt Schiff base hybrid catalyst as electron-transfer mediator were used for the substrate-selective dehydrogenation reaction of various N-heterocycles. The method shows a broad substrate scope and delivers important heterocycles in good-to-excellent yields.

Indexed as

BiomimeticsIronCatalysisFerrous CompoundsOxidation-ReductionFerrous CompoundsIronaerobic oxidationbiomimetic oxidationelectron transfer mediatorheterocyclesiron catalysis

Identifiers

PMID34324754
PMCPMC8518507

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.