ArticleJournal of the American Chemical Society2021
A General Organocatalytic System for Electron Donor-Acceptor Complex Photoactivation and Its Use in Radical Processes.
Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 38 papers.
What it found
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
38 citing papers in PubMed.
- (±)-Rutacycoumarins A and B: two pairs of unprecedented coumarin enantiomers from the aerial part ofPharmaceutical biology · 2026Article
- Photochemical Reaction Discovery Enabled by the Dynamic Speciation of Copper Complexes.Angewandte Chemie (International ed. in English) · 2026Article
- Spatial Orientation-Dependent Double Hydrogen Bond/Photoredox Cooperative Catalysis in Metal-Organic Frameworks.Angewandte Chemie (International ed. in English) · 2026Article
- Association-gated multiphoton activation of inert haloarenes via sequential electron donor-acceptor assembly.Nature communications · 2026Article
- Organic small-molecule-catalyzed carbonylation reactions.Chemical science · 2026Review
- Enantioselective organocatalytic radical alkylation enabled by photoexcitation.Chemical science · 2026Article
- Catalyst-Free Green Synthesis of Dithiocarbamate and Rhodanine Derivatives via C─S and C─N Bond Formation Using N-Substituted Maleimides.Chemistry, an Asian journal · 2026Article
- Topological engineering of covalent organic frameworks enhances photoactivation of electron donor-acceptor complexes via conformational locking.National science review · 2026Article
- Article
- Photoinduced intramolecular S-α-C(spChemical science · 2026Article
- EDA Complex-Mediated C(spEuropean journal of organic chemistry · 2026Article
- EDA Complex-Driven Desaturation of Heterocyclic Carbonyl Compounds Enabled by HFIP.Angewandte Chemie (International ed. in English) · 2025Article
- Amines tuned controllable carbonylation for the synthesis of γ-lactones and 1,4-diones.Nature communications · 2025Article
- EDA photochemistry using continuous flow.Journal of flow chemistry · 2025Review
- Article
- Radical Polarity.Journal of the American Chemical Society · 2024Article
- Cooperative Catalytic Coupling of Benzyl Chlorides and Bromides with Electron-Deficient Alkenes.Organic letters · 2024Article
- Photoinduced Triphenylphosphine and Iodide Salt Promoted Reductive Decarboxylative Coupling.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Dioxygen compatible electron donor-acceptor catalytic system and its enabled aerobic oxygenation.Nature communications · 2024Article
- Regiodivergent Radical Termination for Intermolecular Biocatalytic C-C Bond Formation.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We report herein a modular class of organic catalysts that, acting as donors, can readily form photoactive electron donor-acceptor (EDA) complexes with a variety of radical precursors. Excitation with visible light generates open-shell intermediates under mild conditions, including nonstabilized carbon radicals and nitrogen-centered radicals. The modular nature of the commercially available xanthogenate and dithiocarbamate anion organocatalysts offers a versatile EDA complex catalytic platform for developing mechanistically distinct radical reactions, encompassing redox-neutral and net-reductive processes. Mechanistic investigations, by means of quantum yield determination, established that a closed catalytic cycle is operational for all of the developed radical processes, highlighting the ability of the organic catalysts to turn over and iteratively drive every catalytic cycle. We also demonstrate how the catalysts' stability and the method's high functional group tolerance could be advantageous for the direct radical functionalization of abundant functional groups, including aliphatic carboxylic acids and amines, and for applications in the late-stage elaboration of biorelevant compounds and enantioselective radical catalysis.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.