Evidence map›Paper›PMID 34313367›Full record

ArticleAngewandte Chemie (International ed. in English)2021

Au⋅⋅⋅H-C Hydrogen Bonds as Design Principle in Gold(I) Catalysis.

Heidar Darmandeh, Julian Löffler, Nikolaos V Tzouras, Busra Dereli, Thorsten Scherpf, Kai-Stephan Feichtner, Sofie Vanden Broeck, Kristof Van Hecke, Marina Saab, Catherine S J Cazin and 3 more

Open access · hybridAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.

0numbers the graph read from it
0cells of the map it votes in
16citing papers in PubMed
6.2field-weighted citation impact, top 2% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

16 citing papers in PubMed, 76 citations in OpenAlex.

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  16. Au⋅⋅⋅H-C Hydrogen Bonds as Design Principle in Gold(I) Catalysis.Angewandte Chemie (International ed. in English) · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors at 3 institutions in 3 countries.

Heidar DarmandehChair of Inorganic Chemistry II, Faculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801, Bochum, Germany.ORCID http://orcid.org/0000-0003-2879-9478
Julian LöfflerChair of Inorganic Chemistry II, Faculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801, Bochum, Germany.
Nikolaos V TzourasDepartment of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281, S-3, 9000, Ghent, Belgium.ORCID http://orcid.org/0000-0003-1718-0207
Busra DereliPhysical Sciences & Engineering Division (PSE), KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Saudi Arabia.
Thorsten ScherpfChair of Inorganic Chemistry II, Faculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801, Bochum, Germany.
Kai-Stephan FeichtnerChair of Inorganic Chemistry II, Faculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801, Bochum, Germany.
Sofie Vanden BroeckDepartment of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281, S-3, 9000, Ghent, Belgium.ORCID http://orcid.org/0000-0002-2254-7299
Kristof Van HeckeDepartment of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281, S-3, 9000, Ghent, Belgium.ORCID http://orcid.org/0000-0002-2455-8856
Marina SaabDepartment of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281, S-3, 9000, Ghent, Belgium.
Catherine S J CazinDepartment of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281, S-3, 9000, Ghent, Belgium.ORCID http://orcid.org/0000-0002-9094-8131
Luigi CavalloPhysical Sciences & Engineering Division (PSE), KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Saudi Arabia.ORCID http://orcid.org/0000-0002-1398-338X
Steven P NolanDepartment of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281, S-3, 9000, Ghent, Belgium.ORCID http://orcid.org/0000-0001-9024-2035
Viktoria H GessnerChair of Inorganic Chemistry II, Faculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801, Bochum, Germany.ORCID http://orcid.org/0000-0001-6557-2366
Ghent University · BERuhr University Bochum · DEKing Abdullah University of Science and Technology · SA

Funding

deutsche forschungsgemeinschaft EXC-2033European Research Council 677749special research fund (bof) 01N03217
6 · The paper itself

Abstract

Secondary ligand-metal interactions are decisive in many catalytic transformations. While arene-gold interactions have repeatedly been reported as critical structural feature in many high-performance gold catalysts, we herein report that these interactions can also be replaced by Au⋅⋅⋅H-C hydrogen bonds without suffering any reduction in catalytic performance. Systematic experimental and computational studies on a series of ylide-substituted phosphines featuring either a PPh

Indexed as

catalysisgoldphosphinessecondary interactionssteric and electronic properties

Identifiers

PMID34313367
PMCPMC8518757
OpenAlexW3183956543

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.