ArticleAccounts of chemical research2021
The Story of 5d Metallocorroles: From Metal-Ligand Misfits to New Building Blocks for Cancer Phototherapeutics.
Article in Accounts of chemical research, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed, 47 citations in OpenAlex.
- Rhenium-Selenido Corroles: Reflections on 5d Metalloporphyrins and Metallocorroles as Triplet Emitters and Photosensitizers.Inorganic chemistry · 2025Article
- The role of corroles in modern cancer therapy: innovation and prospects.Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine · 2025Review
- Doubly Stereogenic Sandwich Frameworks: Diastereomeric Metallobiscorroles.Inorganic chemistry · 2025Article
- Inverse Photoemission Spectroscopy of Coinage Metal Corroles: Comparison with Solution-Phase Electrochemistry.ACS organic & inorganic Au · 2024Article
- Gold Tripyrrindione: Redox Chemistry and Reactivity with Dichloromethane.Inorganic chemistry · 2024Article
- Electronic Structure of Metallophlorins: Lessons from Iridium and Gold Phlorin Derivatives.Inorganic chemistry · 2024Article
- Influence of Fluorinated Substituents on the Near-Infrared Phosphorescence of 5d Metallocorroles.ACS organic & inorganic Au · 2023Article
- Queer in Chem: Q&A with Professor Abhik Ghosh.Communications chemistry · 2023Article
- Rhenium Biscorrole Sandwich Compounds: XAS Evidence for a New Coordination Motif.Inorganic chemistry · 2023Article
- Transition-Metal Isocorroles as Singlet Oxygen Sensitizers.Inorganic chemistry · 2023Article
- Luminescence and Palladium: The Odd Couple.Molecules (Basel, Switzerland) · 2023Review
- Phenol- and resorcinol-appended metallocorroles and their derivatization with fluorous tags.Scientific reports · 2022Article
- The Hyperporphyrin Concept: A Contemporary Perspective.JACS Au · 2022Review
- Iridium(VII)-Corrole Terminal Carbides Should Exist as Stable Compounds.ACS organic & inorganic Au · 2022Article
- Comparing Isoelectronic, Quadruple-Bonded Metalloporphyrin and Metallocorrole Dimers: Scalar-Relativistic DFT Calculations Predict a >1 eV Range for Ionization Potential and Electron Affinity.ACS physical chemistry Au · 2022Article
- A DMRG/CASPT2 Investigation of Metallocorroles: Quantifying Ligand Noninnocence in Archetypal 3d and 4d Element Derivatives.JACS Au · 2021Article
- Designer Heme Proteins: Achieving Novel Function with Abiological Heme Analogues.Accounts of chemical research · 2021Article
- The Dog That Didn't Bark: A New Interpretation of Hypsoporphyrin Spectra and the Question of Hypsocorroles.The journal of physical chemistry. A · 2021Article
- Regioselective formylation of rhenium-oxo and gold corroles: substituent effects on optical spectra and redox potentials.RSC advances · 2021Article
- X-ray absorption spectroscopy of exemplary platinum porphyrin and corrole derivatives: metal-RSC advances · 2021Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Porphyrin chemistry is Shakespearean: over a century of study has not withered the field's apparently infinite variety. Heme proteins continually astonish us with novel molecular mechanisms, while new porphyrin analogues bowl us over with unprecedented optical, electronic, and metal-binding properties. Within the latter domain, corroles occupy a special place, exhibiting a unique and rich coordination chemistry. The 5d metallocorroles are arguably the icing on that cake.New Zealand chemist Penny Brothers has used the word "misfit" to describe the interactions of boron, a small atom with a predilection for tetrahedral coordination, and porphyrins, classic square-planar ligands. Steve Jobs lionized misfits as those who see things differently and push humanity forward. Both perspectives have inspired us. The 5d metallocorroles are misfits in that they encapsulate a large 5d transition metal ion within the tight cavity of a contracted porphyrin ligand.Given the steric mismatch inherent in their structures, the syntheses of
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.