ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
Effect of Heterometal-Functionalization and Template Exchange on the Redox Chemistry of Molecular Vanadium Oxides.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
4 citing papers in PubMed.
- Redox Self-Equilibration in Molecular Vanadium Oxide Mixtures Enables Multi-Electron Storage.Angewandte Chemie (International ed. in English) · 2025Article
- Coupled reaction equilibria enable the light-driven formation of metal-functionalized molecular vanadium oxides.Nature communications · 2023Article
- A General Access Route to High-Nuclearity, Metal-Functionalized Molecular Vanadium Oxides.Angewandte Chemie (International ed. in English) · 2022Article
- Effect of Heterometal-Functionalization and Template Exchange on the Redox Chemistry of Molecular Vanadium Oxides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
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Authors and funding
4 authors.
Funding
Abstract
Polyoxometalates (POMs) have emerged as material of interest in many applications such as energy storage and conversion due to their redox activity and molecularly defined structure. However, especially for polyoxovanadates a lack of understanding between structural modifications and physicochemical properties remains. The present study leverages a lacunary dodecavanadate to systematically investigate the electronic effect of heterometal functionalization. While structural distortion affects the stability of the cluster, the redox potentials correlate with the overall cluster charge. Furthermore, we report the first bromide-templated analogue of this cluster family. While the halide anion is crucial for the formation of the cluster, no major effect on the electrochemical properties is observed. By improving the understanding of structure-property relationship in this work, we hope to enable a more predictable tuning of redox-properties of polyoxovandates.
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