ArticleNature chemistry2021
Isolation of a triplet benzene dianion.
Article in Nature chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- The concept of aromaticity after 200 years of benzene.Nature reviews. Chemistry · 2026Review
- Reductive Activation of White Phosphorus to [PAngewandte Chemie (International ed. in English) · 2026Article
- Zerovalent transition-metal inverse-sandwich complexes of a diborataanthracene dianion.Chemical science · 2026Article
- Craig Excited-State Aromaticity in Metallabenzenes: How, When, and Why?Journal of the American Chemical Society · 2026Article
- Inverse-Sandwich Rare Earth Metal Complexes Comprising a Planar Toluene Dianion.Inorganic chemistry · 2026Article
- A Novel Synthetic Pathway to Lanthanide Triple-Decker Complexes: Selective Expansion of a Sandwich Complex by an Insertion Reaction.Angewandte Chemie (International ed. in English) · 2025Article
- ηJournal of the American Chemical Society · 2025Article
- Four-electron reduction of benzene by a samarium(II)-alkyl without the addition of external reducing agents.Nature chemistry · 2025Article
- Linear Inverse Sandwich Complexes of Tetraanionic Benzene Stabilized by Covalent δ-Bonding with Late Lanthanides.Journal of the American Chemical Society · 2024Article
- Tetraphenylpentalenide organolanthanide complexes.Chemical communications (Cambridge, England) · 2024Article
- Article
- Modulation of Slow Magnetic Relaxation in Gd(III)-Tetrahalosemiquinonate Complexes.Chemistry, an Asian journal · 2022Article
- Aromaticity rules.Nature chemistry · 2022Article
- Three-Dimensional Fully π-Conjugated Macrocycles: When 3D-Aromatic and When 2D-Aromatic-in-3D?Journal of the American Chemical Society · 2022Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Baird's rule predicts that molecules with 4n π electrons should be aromatic in the triplet state, but the realization of simple ring systems with such an electronic ground state has been stymied by these molecules' tendency to distort into structures bearing a large singlet-triplet gap. Here, we show that the elusive benzene diradical dianion can be stabilized through creation of a binucleating ligand that enforces a tightly constrained inverse sandwich structure and direct magnetic exchange coupling. Specifically, we report the compounds [K(18-crown-6)(THF)
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