ArticleJournal of the American Chemical Society2021
Bimolecular Coupling in Olefin Metathesis: Correlating Structure and Decomposition for Leading and Emerging Ruthenium-Carbene Catalysts.
Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Reactions of Terminal Olefins With Iron Carbenes.Angewandte Chemie (International ed. in English) · 2026Article
- Ruthenium-based catalysts bearing unsymmetrical NHCs for specific olefin metathesis applications.RSC advances · 2026Article
- On-oligonucleotide olefin metathesis in water.Nature communications · 2026Article
- Synthesis of Cleavable Polyolefins via Ring-Opening Insertion Metathesis Polymerization (ROIMP) of Cyclopentene with Unsaturated Polyester Oligomers.Macromolecules · 2026Article
- Transition Metal Catalysis Drives Innovative Activity-Based Sensing Systems.Trends in chemistry · 2025Article
- Unsaturated Macrolactones from Renewable Feedstocks: Synthesis, Ring-Opening Polymerization and Application Prospects.International journal of molecular sciences · 2025Review
- An Amplificative Detection Approach for Autocatalytic Sensing of Ethylene.Journal of the American Chemical Society · 2025Article
- Olefin Metathesis in Water: Speciation of a Leading Water-Soluble Catalyst Pinpoints Challenges and Opportunities for Chemical Biology.Journal of the American Chemical Society · 2025Article
- "Inverted" Cyclic(Alkyl)(Amino)Carbene (CAAC) Ruthenium Complex Catalyzed Isomerization Metathesis (ISOMET) of Long Chain Olefins to Propylene at Low Ethylene Pressure.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Mesomeric Acceleration Counters Slow Initiation of Ruthenium-CAAC Catalysts for Olefin Metathesis (CAAC = Cyclic (Alkyl)(Amino) Carbene).ACS catalysis · 2023Article
- Water-Accelerated Decomposition of Olefin Metathesis Catalysts.ACS catalysis · 2023Article
- Fluorescent organometallic dyads and triads: establishing spatial relationships.Chemical science · 2023Article
- Theoretical Perspectives in Organocatalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Review
- Catalytic Decomposition of Long-Chain Olefins to Propylene via Isomerization-Metathesis Using Latent Bicyclic (Alkyl)(Amino)Carbene-Ruthenium Olefin Metathesis Catalysts.Angewandte Chemie (International ed. in English) · 2022Article
- The Janus face of high trans-effect carbenes in olefin metathesis: gateway to both productivity and decomposition.Chemical science · 2022Article
- Routes to High-Performing Ruthenium-Iodide Catalysts for Olefin Metathesis: Ligand Lability Is Key to Efficient Halide Exchange.Organometallics · 2021Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Bimolecular catalyst decomposition is a fundamental, long-standing challenge in olefin metathesis. Emerging ruthenium-cyclic(alkyl)(amino)carbene (CAAC) catalysts, which enable breakthrough advances in productivity and general robustness, are now known to be extraordinarily susceptible to this pathway. The details of the process, however, have hitherto been obscure. The present study provides the first detailed mechanistic insights into the steric and electronic factors that govern bimolecular decomposition. Described is a combined experimental and theoretical study that probes decomposition of the key active species, RuCl
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