Evidence map›Paper›PMID 34268851›Full record

ArticleAngewandte Chemie (International ed. in English)2021

Carbonyl Hypoiodites as Extremely Strong Halogen Bond Donors.

Shilin Yu, Jas S Ward, Khai-Nghi Truong, Kari Rissanen

Open access · hybridAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.

0numbers the graph read from it
0cells of the map it votes in
9citing papers in PubMed
11.8field-weighted citation impact, top 1% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

9 citing papers in PubMed, 60 citations in OpenAlex.

  1. Article
  2. Article
  3. Highly Enantioselective Organocatalysis with Bidentate Halogen Bond Donors.Angewandte Chemie (International ed. in English) · 2025
    Article
  4. Article
  5. Article
  6. Article
  7. Halogen Bonds of Halogen(I) Ions─Where Are We and Where to Go?Journal of the American Chemical Society · 2024
    Review
  8. Article
  9. Carbonyl Hypoiodites as Extremely Strong Halogen Bond Donors.Angewandte Chemie (International ed. in English) · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 1 institution in 1 country.

Shilin YuDepartment of Chemistry, University of Jyvaskyla, Survontie 9 B, 40014, Jyväskylä, Finland.ORCID http://orcid.org/0000-0003-3028-799X
Jas S WardDepartment of Chemistry, University of Jyvaskyla, Survontie 9 B, 40014, Jyväskylä, Finland.ORCID http://orcid.org/0000-0001-9089-9643
Khai-Nghi TruongDepartment of Chemistry, University of Jyvaskyla, Survontie 9 B, 40014, Jyväskylä, Finland.ORCID http://orcid.org/0000-0001-9764-7350
Kari RissanenDepartment of Chemistry, University of Jyvaskyla, Survontie 9 B, 40014, Jyväskylä, Finland.ORCID http://orcid.org/0000-0002-7282-8419
University of Jyväskylä · FI

Funding

Magnus Ehrnroothin SäätiöSuomen Akatemia, luonnontieteiden ja tekniikan tutkimuksen toimikunta 317259Suomen Kulttuurirahasto 00201148
6 · The paper itself

Abstract

Neutral halogen-bonded O-I-N complexes were prepared from in situ formed carbonyl hypoiodites and aromatic organic bases. The carbonyl hypoiodites have a strongly polarized iodine atom with larger σ-holes than any known uncharged halogen bond donor. Modulating the Lewis basicity of the selected pyridine derivatives and carboxylates leads to halogen-bonded complexes where the classical O-I⋅⋅⋅N halogen bond transforms more into a halogen-bonded COO

Indexed as

halogen bondinghypoioditeNMR spectroscopypyridinesupramolecular chemistry

Identifiers

PMID34268851
PMCPMC8518949
OpenAlexW3182164889

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.