ArticleChemical communications (Cambridge, England)2021
Fast synthesis and redox switching of di- and tetra-substituted bisthioxanthylidene overcrowded alkenes.
Article in Chemical communications (Cambridge, England), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Lucigenin: a strongly oxidizing dicationic photocatalyst for the direct azolation of arenes.Chemical science · 2026Article
- Sulfone-functionalized stereoisomeric [3]radialene displays guest induced modulation of porous frameworks and critical crystallization-induced near-infrared emission.Chemical science · 2026Article
- Light-gated redox switching and actuation in polymer hydrogels.Nature communications · 2025Article
- Multi-State Redox and Light-Driven Switching of Pseudorotaxanation and Cation Shuttling.Journal of the American Chemical Society · 2025Article
- A Multiresponsive Ferrocene-Based Chiral Overcrowded Alkene Twisting Liquid Crystals.Angewandte Chemie (International ed. in English) · 2025Article
- Mix and Match Tuning of the Conformational and Multistate Redox Switching Properties of an Overcrowded Alkene.Journal of the American Chemical Society · 2024Article
- Redox-Switchable Aromaticity in a Helically Extended Indeno[2,1-Journal of the American Chemical Society · 2024Article
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A rapid and efficient method for the synthesis of overcrowded alkenes using (trimethylsilyl)diazomethane provides a range of substituted bisthioxanthylidenes. We show large conformational redox switching from folded to orthogonal states, which tolerates many substitution patterns. The facile access to bisthioxanthylidene switches with the potential for further functionalization, in combination with the reliable redox chemistry, provides major opportunities for the design of electrochemically responsive systems.
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Registered trials
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