ArticleNature chemistry2021
Visible light enables catalytic formation of weak chemical bonds with molecular hydrogen.
Article in Nature chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Multifunctional Photocatalysts Based on Half-Sandwich Cyclometalated Ir(III) Complexes with π-Extended Ligands.Inorganic chemistry · 2026Article
- On the mechanism of photodriven hydrogenations of NProceedings of the National Academy of Sciences of the United States of America · 2025Article
- Photosynthesis of NHAngewandte Chemie (International ed. in English) · 2025Article
- Catalysis in the Excited State: Bringing Innate Transition Metal Photochemistry into Play.ACS catalysis · 2025Review
- Visible-Light-Driven Catalytic Dehalogenation of Trichloroacetic Acid and α-Halocarbonyl Compounds: Multiple Roles of Copper.ACS catalysis · 2025Article
- Reductive Photocatalytic Proton-Coupled Electron Transfer by a Zirconium-Based Molecular Platform.Angewandte Chemie (International ed. in English) · 2024Article
- Shuttle HAT for mild alkene transfer hydrofunctionalization.Nature communications · 2024Article
- Intermolecular Proton-Coupled Electron Transfer Reactivity from a Persistent Charge-Transfer State for Reductive Photoelectrocatalysis.Journal of the American Chemical Society · 2024Article
- Selective Hydrogenation of Azobenzene to Hydrazobenzene via Proton-Coupled Electron Transfer from a Polyoxotungstate Cluster.JACS Au · 2024Article
- Asymmetric arene hydrogenation: towards sustainability and application.Chemical Society reviews · 2023Review
- Advancing electrocatalytic nitrogen fixation: insights from molecular systems.Faraday discussions · 2023Article
- Sm(II)-Mediated Proton-Coupled Electron Transfer: Quantifying Very Weak N-H and O-H Homolytic Bond Strengths and Factors Controlling Them.Journal of the American Chemical Society · 2022Article
- Energy- and atom-efficient chemical synthesis with endergonic photocatalysis.Nature reviews. Chemistry · 2022Review
- Radical Activation of N-H and O-H Bonds at Bismuth(II).Journal of the American Chemical Society · 2022Article
- Visible-Light-Promoted Iridium(III)-Catalyzed Acceptorless Dehydrogenation of N-Heterocycles at Room Temperature.ACS catalysis · 2022Article
- Light-driven oxidation of CHRSC advances · 2022Article
- Article
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The synthesis of weak chemical bonds at or near thermodynamic potential is a fundamental challenge in chemistry, with applications ranging from catalysis to biology to energy science. Proton-coupled electron transfer using molecular hydrogen is an attractive strategy for synthesizing weak element-hydrogen bonds, but the intrinsic thermodynamics presents a challenge for reactivity. Here we describe the direct photocatalytic synthesis of extremely weak element-hydrogen bonds of metal amido and metal imido complexes, as well as organic compounds with bond dissociation free energies as low as 31 kcal mol
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