Evidence map›Paper›PMID 34253024›Full record

ArticleJournal of the American Chemical Society2021

Interfacial Acid-Base Equilibria and Electric Fields Concurrently Probed by

Murielle F Delley, Eva M Nichols, James M Mayer

Open access · greenAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.

0numbers the graph read from it
0cells of the map it votes in
20citing papers in PubMed
5.1field-weighted citation impact, top 2% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

20 citing papers in PubMed, 78 citations in OpenAlex.

  1. Fractional charge density functional theory elucidates electro-inductive and electric field effects at electrochemical interfaces.Proceedings of the National Academy of Sciences of the United States of America · 2026
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  7. Operando Raman characterization of unique electroinduced molecular tautomerization in zero-gap electrolyzers promotes COProceedings of the National Academy of Sciences of the United States of America · 2025
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  17. Anion-π catalysis on carbon allotropes.Beilstein journal of organic chemistry · 2023
    Review
  18. Article
  19. Electrolyte Cation Effects on Interfacial Acidity and Electric Fields.The journal of physical chemistry. C, Nanomaterials and interfaces · 2022
    Article
  20. Article
4 · The record

Corrections and comments

5 · Who and what money

Authors and funding

3 authors at 3 institutions in 3 countries.

Murielle F DelleyDepartment of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel, Switzerland.ORCID 0000-0001-6450-5540
Eva M NicholsDepartment of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada.ORCID 0000-0002-3718-7273
James M MayerDepartment of Chemistry, Yale University, New Haven, Connecticut 06520-8107, United States.ORCID 0000-0002-3943-5250
University of Basel · CHUniversity of British Columbia · CAYale University · US

Funding

UNDERSTANDING METAL MEDIATED C-H AND O-H BOND OXIDATIONSR01GM050422 · NIGMS · YALE UNIVERSITY · PI MAYER, JAMES M · 1995 to 2020
$6.1M
Model Systems for the Elucidation of Parameters Governing Electron BifurcationF32GM129902 · NIGMS · YALE UNIVERSITY · PI NICHOLS, EVA MEGAN · 2018 to 2019
$114k
NIGMS NIH HHS F32 GM129902NIGMS NIH HHS R01 GM050422
6 · The paper itself

Abstract

Understanding how applied potentials and electrolyte solution conditions affect interfacial proton (charge) transfers at electrode surfaces is critical for electrochemical technologies. Herein, we examine mixed self-assembled monolayers (SAMs) of 4-mercaptobenzoic acid (4-MBA) and 4-mercaptobenzonitrile (4-MBN) on gold using

Indexed as

BenzoatesElectricityGoldHydrogen-Ion ConcentrationMolecular StructureNitrilesSpectrophotometry, InfraredSulfhydryl CompoundsSurface Properties4-mercaptobenzoateBenzoatesbenzonitrileGoldNitrilesSulfhydryl Compounds

Identifiers

PMID34253024
PMCPMC12439667
OpenAlexW3178015363

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.