ArticleACS omega2021
Assembling Hybrid Energetic Materials with Controllable Interfacial Microstructures by Electrospray.
Article in ACS omega, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed, 27 citations in OpenAlex.
- Novel Approach for the Fabrication of Composite Rocket Propellant: Increased Homogeneity and Its Influence on SRP Behaviour.Materials (Basel, Switzerland) · 2026Article
- Abrupt Transition of Nanothermite Reactivity: The Roles of Loading Density, Microstructure and Ingredients.Molecules (Basel, Switzerland) · 2025Article
- Ti/CuO Nanothermite Doped with Secondary Energetic Materials: A Study of Combustion Parameters.Molecules (Basel, Switzerland) · 2024Article
- Evaluation of High-Performance Polyether Ether Ketone Polymer Treated with Piranha Solution and Epigallocatechin-3-Gallate Coating.BioMed research international · 2024Article
- Preparation and Properties of Spherical CL-20 Composites.ACS omega · 2022Article
- Preparation of Core-Shell-Structured RDX@PVDF Microspheres with Improved Thermal Stability and Decreased Mechanical Sensitivity.Polymers · 2022Article
- Article
- Recent Progress on Synthesis, Characterization, and Performance of Energetic Cocrystals: A Review.Molecules (Basel, Switzerland) · 2022Review
- Quo Vadis, Nanothermite? A Review of Recent Progress.Materials (Basel, Switzerland) · 2022Review
- Progress in Electrohydrodynamic Atomization Preparation of Energetic Materials with Controlled Microstructures.Molecules (Basel, Switzerland) · 2022Review
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Constructing hybrid energetic materials (HEMs) consisting of nanothermites and organic high explosives is an efficient strategy to regulate the reactivity of energetic composites. To investigate the role of interfacial microstructures in determining the reactivity of HEMs, we employ electrospray, one ramification of electrohydrodynamic atomization, to assemble Al/CuO and hexanitrohexaazaisowurtzitane (CL-20) into composites with various morphologies from different solvent systems. The morphology and compositional information of the assembled clay-like or granular HEMs, which are obtained from ketone, ester, or mixtures of alcohol and ether, are confirmed by scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). The phase transition of CL-20 due to the fast evaporation of charged droplets and insufficient time for recrystallization is studied by Fourier transform infrared spectroscopy (FTIR). Thermogravimetric-differential scanning calorimetry (TG-DSC) is applied to investigate the thermodynamic behaviors and synergistic effect of the nanothermite and high explosive. Enhancements in combustion performance and pressurization characteristics of the as-sprayed HEMs have been observed through open burn tests and pressure cell tests. Granular HEMs show high gas generation and high pressurization rate, while nitrocellulose (NC) fibers existing in the clay-like HEMs would weaken the reactivity to a certain extent. HEMs obtained from the mixture of
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