ArticleAdvanced materials (Deerfield Beach, Fla.)2021
High-Entropy Metal-Organic Frameworks for Highly Reversible Sodium Storage.
Article in Advanced materials (Deerfield Beach, Fla.), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 40 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
40 citing papers in PubMed, 337 citations in OpenAlex.
- A Review on Jahn-Teller Distortions in Prussian Blue Analogs Molecular Magnets.Chemical record (New York, N.Y.) · 2026Review
- Entropy-Engineered Multi-Metallic MOFs Unlock High-Performance Ammonium-Ion Storage.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Universal Phase Engineering of High-Entropy Sulfides for Stable Sodium-Ion Storage With Ultra-High Capacity and Ultra-Fast Kinetics.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- High-Entropy Engineering of Phosphate Based Polyanion Cathode Materials for Sodium-Ion Batteries: Advances and Perspectives.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
- High-Entropy Polymer Electrode for Fast Rechargeable Batteries.Angewandte Chemie (International ed. in English) · 2026Article
- Surface Gradient Doping Enables High-Capacity and Long-Life Manganese-Based Prussian Blue Cathodes for Sodium-Ion Batteries.Angewandte Chemie (International ed. in English) · 2026Article
- Unlocking the capacity of Mn-based Prussian blue cathodes in capacitive deionization.Nature communications · 2026Article
- Engineering non-interfacial hydrogen spillover in a NiNature communications · 2026Article
- Layered Porous Nanocubes: Harnessing Trimetallic PBA@WSACS applied materials & interfaces · 2026Article
- Ultralow-Frequency Epsilon-Near-Zero States in 3D-Printed High-Entropy Alloy Metacomposites for Ultra-Thin Perfect RF Absorption.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- High-Entropy Double Perovskites with Tailored Multichannel Luminescence.Journal of the American Chemical Society · 2025Article
- Synthesis-Driven Functionality in High-Entropy Materials.Small (Weinheim an der Bergstrasse, Germany) · 2025Review
- Computational Analysis of the Energetic Stability of High-Entropy Structures of a Prototypical Lanthanide-Based Metal-Organic Framework.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Formulating cathode materials based on high-entropy strategies for sodium-ion batteries.Chemical science · 2025Review
- Review
- Ligand Field-Induced Dual Active Sites Enhance Redox Potential of Nickel Hexacyanoferrate for Ammonium Ion Storage.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Suppressing the Phase Transformation in Cubic Prussian Blue Analogues via a High-Entropy Strategy for Efficient Zinc-Ion Storage.Materials (Basel, Switzerland) · 2025Article
- A Perspective on the Origin of High-Entropy Solid Electrolytes.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Prussian Blue Analogues as Anode Materials for Battery Applications: Complexities and Horizons.Chemistry of materials : a publication of the American Chemical Society · 2025Review
- Understanding capacity fading from structural degradation in Prussian blue analogues for wide-temperature sodium-ion cylindrical battery.Nature communications · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
11 authors at 2 institutions in 2 countries.
Funding
Abstract
Prussian blue analogues (PBAs) are reported to be efficient sodium storage materials because of the unique advantages of their metal-organic framework structure. However, the issues of low specific capacity and poor reversibility, caused by phase transitions during charge/discharge cycling, have thus far limited the applicability of these materials. Herein, a new approach is presented to substantially improve the electrochemical properties of PBAs by introducing high entropy into the crystal structure. To achieve this, five different metal species are introduced, sharing the same nitrogen-coordinated site, thereby increasing the configurational entropy of the system beyond 1.5R. By careful selection of the elements, high-entropy PBA (HE-PBA) presents a quasi-zero-strain reaction mechanism, resulting in increased cycling stability and rate capability. The key to such improvement lies in the high entropy and associated effects as well as the presence of several active redox centers. The gassing behavior of PBAs is also reported. Evolution of dimeric cyanogen due to oxidation of the cyanide ligands is detected, which can be attributed to the structural degradation of HE-PBA during battery operation. By optimizing the electrochemical window, a Coulombic efficiency of nearly 100% is retained after cycling for more than 3000 cycles.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.