Evidence map›Paper›PMID 34244595›Full record

ArticleScientific reports2021

Surface and bulk modifications of amphibole asbestos in mimicked gamble's solution at acidic PH.

Alessandro Pacella, Paolo Ballirano, Marzia Fantauzzi, Antonella Rossi, Elisa Nardi, Giancarlo Capitani, Lorenzo Arrizza, Maria Rita Montereali

Open access · goldAbstract read
In one paragraph

Article in Scientific reports, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
1.6field-weighted citation impact, top 16% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed, 15 citations in OpenAlex.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 6 institutions in 1 country.

Alessandro PacellaDipartimento di Scienze della Terra and Laboratorio Rettorale Fibre e Particolato Inorganico, Sapienza Università di Roma, P.le A. Moro 5, 00185, Rome, Italy. alessandro.pacella@uniroma1.it.
Paolo BalliranoDipartimento di Scienze della Terra and Laboratorio Rettorale Fibre e Particolato Inorganico, Sapienza Università di Roma, P.le A. Moro 5, 00185, Rome, Italy.
Marzia FantauzziDipartimento di Scienze Chimiche e Geologiche, INSTM Research Unit, Centro Grandi Strumenti, Università di Cagliari, 09042, Monserrato, Cagliari, Italy.
Antonella RossiDipartimento di Scienze Chimiche e Geologiche, INSTM Research Unit, Centro Grandi Strumenti, Università di Cagliari, 09042, Monserrato, Cagliari, Italy.
Elisa NardiIstituto Superiore per la Protezione e la Ricerca Ambientale (ISPRA), via Vitaliano Brancati 48, 00144, Roma, Italy.
Giancarlo CapitaniDipartimento di Scienze dell'Ambiente e di Scienze della Terra, Università degli Studi di Milano-Bicocca, Piazza della Scienza 4, 20126, Milano, Italy.
Lorenzo ArrizzaCentro di Microscopie, Università degli Studi dell'Aquila, Via Vetoio (Coppito 1, Edificio "Renato Ricamo"), 67100, Coppito, L'Aquila, Italy.
Maria Rita MonterealiENEA, C.R. Casaccia via Anguillarese 301,S. Maria Di Galeria, 00123, Roma, Italy.
Sapienza University of Rome · ITUniversity of Cagliari · ITIstituto Superiore per la Protezione e la Ricerca Ambientale · ITNational Agency for New Technologies, Energy and Sustainable Economic Development · ITUniversity of L'Aquila · ITUniversity of Milano-Bicocca · IT

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

This study aimed at investigating the surface modifications occurring on amphibole asbestos (crocidolite and tremolite) during leaching in a mimicked Gamble's solution at pH of 4.5 and T = 37 °C, from 1 h up to 720 h. Results showed that the fibre dissolution starts with the release of cations prevalently allocated at the various M- and (eventually) A-sites of the amphibole structure (incongruent dissolution). The amount of released silicon, normalized to fibre surface area, highlighted a leaching faster for the crocidolite sample, about twenty times higher than that of tremolite. Besides, the fast alteration of crocidolite promotes the occurrence of Fe centres in proximity of the fibre surface, or possibly even exposed, particularly in the form of Fe(II), of which the bulk is enriched with respect to the oxidized surface. Conversely, for tremolite fibres the very slow fibre dissolution prevents the underlying cations of the bulk to be exposed on the mineral surface, and the iron oxidation, faster than the leaching process, significantly depletes the surface Fe(II) centres initially present. Results of this work may contribute to unravel possible correlations between surface properties of amphibole asbestos and its long-term toxicity.

Identifiers

PMID34244595
PMCPMC8270982
OpenAlexW3182100082

What OpenQuestion holds

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LicenceCC BY
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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.