ArticleChemical reviews2021
Cathodic Corrosion of Metal Electrodes-How to Prevent It in Electroorganic Synthesis.
Article in Chemical reviews, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 31 papers.
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Who cites it
31 citing papers in PubMed.
- Deep reduction in electrosynthesis.Nature chemistry · 2026Review
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- Electrochemical Synthesis of 1,2-SubstitutedOrganic letters · 2026Article
- Quaternary Ammonium Additives as Dual Inhibitors of Hydrogen Evolution and Cathodic Corrosion in Aqueous Electrosynthesis.ACS electrochemistry · 2026Article
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- Electrochemical Dehydration Reaction.ChemSusChem · 2025Review
- Fe-electrocatalytic deoxygenative Giese reaction.Nature communications · 2025Article
- Electrochemical Dehydration of Sulfonic Acids to Their Anhydrides.The Journal of organic chemistry · 2025Article
- Cement-Based Electrochemical Systems for Structural Energy Storage: Progress and Prospects.Materials (Basel, Switzerland) · 2025Review
- Quaternary Ammonium Salts as Supporting Electrolytes in Cathodic Reductions: An Analysis of Their Electrochemical Stability.The journal of physical chemistry. B · 2025Article
- All Electrochemical Synthesis of Performic Acid Starting from COChemSusChem · 2025Article
- TEMPO-Mediated Paired Electrosynthesis of Ethylene Glycol from Formaldehyde and Methanol at High Current Densities.ChemSusChem · 2025Article
- Simple and versatile electrochemical synthesis of highly substituted 2,1-benzisoxazoles.Organic & biomolecular chemistry · 2025Article
- Hydride Formation and Decomposition on Cu(111) in HClOJournal of the American Chemical Society · 2025Article
- Sustainable corrosion prevention of mild steel in acidic media withRSC advances · 2025Article
- ZnO doped PAMAM for asphalt improvement as anti-corrosive coatings.Scientific reports · 2024Article
- Highly Selective Electrosynthesis of 1Organic process research & development · 2024Article
- Practical electrochemical hydrogenation of nitriles at the nickel foam cathode.Green chemistry : an international journal and green chemistry resource : GC · 2024Article
- Simple electrochemical synthesis of cyclic hydroxamic acids by reduction of nitroarenes.Chemical communications (Cambridge, England) · 2024Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The critical aspects of the corrosion of metal electrodes in cathodic reductions are covered. We discuss the involved mechanisms including alloying with alkali metals, cathodic etching in aqueous and aprotic media, and formation of metal hydrides and organometallics. Successful approaches that have been implemented to suppress cathodic corrosion are reviewed. We present several examples from electroorganic synthesis where the clever use of alloys instead of soft neat heavy metals and the application of protective cationic additives have allowed to successfully exploit these materials as cathodes. Because of the high overpotential for the hydrogen evolution reaction, such cathodes can contribute toward more sustainable green synthetic processes. The reported strategies expand the applications of organic electrosynthesis because a more negative regime is accessible within protic media and common metal poisons, e.g., sulfur-containing substrates, are compatible with these cathodes. The strongly diminished hydrogen evolution side reaction paves the way for more efficient reductive electroorganic conversions.
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Registered trials
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