ArticleAngewandte Chemie (International ed. in English)2021
Chromoselective Synthesis of Sulfonyl Chlorides and Sulfonamides with Potassium Poly(heptazine imide) Photocatalyst.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed, 51 citations in OpenAlex.
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- Chemical Upcycling of Polyphenylene Sulfide at Room Temperature.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Review
- Ligand-Enabled Photocatalytic Reactivity of Iron(III) Halide Salts with Cyan and Green Light.Organic letters · 2026Article
- Organic Synthesis Mediated by Carbon Nitride Photocatalysis and Photocharged Carbon Nitrides.Accounts of chemical research · 2026Article
- Coaxial Dielectric Spectroscopy as an In-Line Process Analytical Technique for Reaction Monitoring.Organic process research & development · 2023Article
- Nature of Luminescence and Pharmacological Activity of Sulfaguanidine.Molecules (Basel, Switzerland) · 2023Article
- Green Light Photoelectrocatalysis with Sulfur-Doped Carbon Nitride: Using Triazole-Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Progress in Development of Photocatalytic Processes for Synthesis of Fuels and Organic Compounds under Outdoor Solar Light.Energy & fuels : an American Chemical Society journal · 2022Review
- Red edge effect and chromoselective photocatalysis with amorphous covalent triazine-based frameworks.Nature communications · 2022Article
- Synthesis of Sulfonyl Chlorides from Aryldiazonium Salts Mediated by a Heterogeneous Potassium Poly(heptazine imide) Photocatalyst.ACS organic & inorganic Au · 2022Article
- Controlling Chemoselectivity of Catalytic Hydroboration with Light.Angewandte Chemie (International ed. in English) · 2022Article
- Chromoselective Synthesis of Sulfonyl Chlorides and Sulfonamides with Potassium Poly(heptazine imide) Photocatalyst.Angewandte Chemie (International ed. in English) · 2021Article
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Authors and funding
6 authors at 2 institutions in 1 country.
Funding
Abstract
Among external stimuli used to promote a chemical reaction, photocatalysis possesses a unique one-light. Photons are traceless reagents that provide an exclusive opportunity to alter chemoselectivity of the photocatalytic reaction varying the color of incident light. This strategy may be implemented by using a sensitizer capable to activate a specific reaction pathway depending on the excitation light. Herein, we use potassium poly(heptazine imide) (K-PHI), a type of carbon nitride, to generate selectively three different products from S-arylthioacetates simply varying the excitation light and otherwise identical conditions. Namely, arylchlorides are produced under UV/purple, sulfonyl chlorides with blue/white, and diaryldisulfides at green to red light. A combination of the negatively charged polyanion, highly positive potential of the valence band, presence of intraband states, ability to sensitize singlet oxygen, and multi-electron transfer is shown to enable this chromoselective conversion of thioacetates.
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