ArticleNature communications2021
Frustrated flexibility in metal-organic frameworks.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 31 papers.
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Who cites it
31 citing papers in PubMed.
- Development and comparative investigation of structural and functional properties of Ni-based metal-organic frameworks designed for photocatalytic hydrogen production.RSC advances · 2026Article
- Programmable Guest-Induced 5-Phase-Transition Topological Reconstructions of Cobalt Formate Metal-Organic Frameworks.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- A 3D conductive amorphous unsaturated-ligand MIL-68(Fe) MOF as room-temperature HNature communications · 2026Article
- Facile and Fast Microwave-Assisted Synthesis of Metalated PCN-222 for Light-Driven Hydrogen Evolution Reaction.ACS omega · 2026Article
- Lone-pair-electron-governed gas-recognizable flexibility in a stable MOF for boosting CNature communications · 2026Article
- Functional Chain Engineering in MOFs: Balancing Pore Size and Affinity for Noble Gas Separation.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Deciphering the stimuli-responsive behavior of TPPE-incorporated flexible metal-organic frameworks.Chemical science · 2026Article
- Flexible Metal-Organic Frameworks for Gas Handling Operations of CONano-micro letters · 2026Review
- Trapping a Metastable Node in an Amorphous Metal-Organic Framework.Angewandte Chemie (International ed. in English) · 2026Article
- Deciphering the guest-free crystal structures and thermal breathing of the flexible metal-organic frameworks ZIF-7 and ZIF-9.Chemical science · 2026Article
- Precise modulation of MOF pore structures via functional group dimensions and spatial configuration for membrane separation.Science advances · 2026Article
- Bioinspired synthesis of ultra-small copper-aspartate BioMOF nanodots using sodium caseinate for targeted curcumin delivery.Scientific reports · 2025Article
- Elucidating the Structure and the Impact of Synthesis Methods on the Flexibility of the Metal-Organic Framework MIL-88 A (Fe) During Water Capture.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Practical Considerations in the Design and Use of Non-Crystalline Metal-Organic Frameworks.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- sln-Topological Covalent Organic Frameworks with Shape Dimorphism and Dipolar Rotors.Journal of the American Chemical Society · 2025Article
- Zero- to One-Dimensional Transformation in a Highly Porous Metal-Organic Framework to Enhance Physicochemical Properties.Journal of the American Chemical Society · 2025Article
- COSmall (Weinheim an der Bergstrasse, Germany) · 2025Article
- Adsorptive-dissolution of ONature communications · 2024Article
- Water Sorption on Isoreticular CPO-27-Type MOFs: From Discrete Sorption Sites to Water-Bridge-Mediated Pore Condensation.Nanomaterials (Basel, Switzerland) · 2024Article
- Enhanced elastic stability of a topologically disordered crystalline metal-organic framework.Nature materials · 2024Article
Corrections and comments
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Authors and funding
14 authors.
Funding
Abstract
Stimuli-responsive flexible metal-organic frameworks (MOFs) remain at the forefront of porous materials research due to their enormous potential for various technological applications. Here, we introduce the concept of frustrated flexibility in MOFs, which arises from an incompatibility of intra-framework dispersion forces with the geometrical constraints of the inorganic building units. Controlled by appropriate linker functionalization with dispersion energy donating alkoxy groups, this approach results in a series of MOFs exhibiting a new type of guest- and temperature-responsive structural flexibility characterized by reversible loss and recovery of crystalline order under full retention of framework connectivity and topology. The stimuli-dependent phase change of the frustrated MOFs involves non-correlated deformations of their inorganic building unit, as probed by a combination of global and local structure techniques together with computer simulations. Frustrated flexibility may be a common phenomenon in MOF structures, which are commonly regarded as rigid, and thus may be of crucial importance for the performance of these materials in various applications.
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Registered trials
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