ArticleNature communications2021
A curved host and second guest cooperatively inhibit the dynamic motion of corannulene.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
18 citing papers in PubMed, 50 citations in OpenAlex.
- London Dispersion Governs Stereochemistry, Stability, and Self-Sorting in a System of MJournal of the American Chemical Society · 2026Article
- Charge engineering controls cooperative assembly and loading in protein host-guest complexes.Journal of materials chemistry. B · 2025Article
- Fluoride Enhances Alcohol Binding Within a Trigonal-Prismatic Metal-Organic Capsule.Angewandte Chemie (International ed. in English) · 2025Article
- Formation of a PdJACS Au · 2025Article
- A Bis-Perylene Diimide Macrocycle Chiroptical Switch.Angewandte Chemie (International ed. in English) · 2025Article
- Paramagnetic Cage-Type Co(II) Complexes of Chiral Macrocycles: Enantio- and Size-Selective Binding of Guest Molecules.Inorganic chemistry · 2025Article
- Chiral PdAngewandte Chemie (International ed. in English) · 2025Article
- CageCavityCalc (Journal of chemical information and modeling · 2024Article
- Enantiopure trigonal bipyramidal coordination cages templated by in situ self-organized DNature communications · 2024Article
- Mutual induced fit transition structure stabilization of corannulene's bowl-to-bowl inversion in a perylene bisimide cyclophane.Chemical science · 2024Article
- A Coordination-Driven Self-Assembly and NIR Photothermal Conversion Study of Organometallic Handcuffs.Molecules (Basel, Switzerland) · 2023Article
- Subtle Stereochemical Effects Influence Binding and Purification Abilities of an FeJournal of the American Chemical Society · 2023Article
- Tetramine Aspect Ratio and Flexibility Determine Framework Symmetry for ZnAngewandte Chemie (International ed. in English) · 2023Article
- Sequential Formation of Heteroternary Cucurbit[10]uril (CB[10]) Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence.Chem · 2022Article
- Solvent Drives Switching between Λ and Δ Metal Center Stereochemistry of MJournal of the American Chemical Society · 2022Article
- Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Review
- Cooperativity of steric bulk and H-bonding in coordination sphere engineering: heteroleptic PdChemical science · 2022Article
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Biomolecular systems show how host-guest binding can induce changes in molecular behavior, which in turn impact the functions of the system. Here we report an artificial host-guest system where dynamic adaptation during guest binding alters both host conformation and guest dynamics. The self-assembled cage host employed here possesses concave walls and a chirotopic cavity. Complementarity between the curved surfaces of fullerenes and the inner surface of the host cavity leads the host to reconfigure stereochemically in order to bind these guests optimally. The curved molecule corannulene undergoes rapid bowl-to-bowl inversion at room temperature. Its inversion barrier is increased upon binding, however, and increased further upon formation of a ternary complex, where corannulene and a cycloalkane are both bound together. The chiral nature of the host also leads to clear differences in the NMR spectra of ternary complexes involving corannulene and one or the other enantiomer of a chiral guest, which enables the determination of enantiomeric excess by NMR.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.