ArticleNature reviews. Physics2021
Using X-ray free-electron lasers for spectroscopy of molecular catalysts and metalloenzymes.
Article in Nature reviews. Physics, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 41 papers.
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Who cites it
41 citing papers in PubMed.
- Optimisation of measurement and data analysis of time-resolved X-ray absorption spectroscopy of thin film organic semiconductors.Faraday discussions · 2026Article
- Pursuing Heteroleptic Ligand Design Principles for Photoactive Fe Complexes with Ultrafast X-ray Emission and Variable-Temperature Optical Spectroscopies.Journal of the American Chemical Society · 2026Article
- Improved image reconstruction in coherent diffraction imaging using self-seeded XFEL pulses.Journal of synchrotron radiation · 2026Article
- From Local Atomic Structure to X-ray Spectra: Absorber-Centric Machine-Learning Encoding.The journal of physical chemistry. A · 2026Article
- Can ferric-oxyl excited states explain elongated iron-oxygen bonds in heme peroxidase catalytic intermediates?Nature communications · 2026Article
- Development of arrival-time diagnostic tool for X-ray pump-probe experiments at Shanghai Soft X-ray Free Electron Laser.Journal of synchrotron radiation · 2026Article
- Demonstration of time-resolved Fe K-edge XANES with a self-seeded X-ray free-electron laser at PAL-XFEL.Scientific reports · 2025Article
- Dispersive X-ray absorption spectroscopy using independent grazing-incidence focusing and convexly bent Bragg-crystal dispersing optics.Journal of synchrotron radiation · 2025Article
- A high-energy Laue X-ray emission spectrometer at the FXE instrument at the European XFEL.Journal of synchrotron radiation · 2025Article
- X-ray Absorption Spectroscopy of Dilute Metalloenzymes at X-ray Free-Electron Lasers in a Shot-by-Shot Mode.The journal of physical chemistry letters · 2025Article
- Probing soft X-ray induced photoreduction of a model Mn-complex at cryogenic conditions.Journal of synchrotron radiation · 2025Article
- Ultrafast Mapping of Electronic and Nuclear Structure in the Photo Dissociation of Nitrogen Dioxide.The journal of physical chemistry letters · 2024Article
- Stimulated X-ray emission spectroscopy.Photosynthesis research · 2024Review
- How to Assess and Predict Electrical Double Layer Properties. Implications for Electrocatalysis.Chemical reviews · 2024Review
- Excited-State Identification of a Nickel-Bipyridine Photocatalyst by Time-Resolved X-ray Absorption Spectroscopy.The journal of physical chemistry letters · 2024Article
- A sub-100 nm thickness flat jet for extreme ultraviolet to soft X-ray absorption spectroscopy.Journal of synchrotron radiation · 2024Article
- X-ray free-electron laser induced acoustic microscopy (XFELAM).Photoacoustics · 2024Article
- Toward ultrafast soft x-ray spectroscopy of organic photovoltaic devices.Structural dynamics (Melville, N.Y.) · 2024Article
- Thinner than a knife's edge: 3D-printed liquid sheet jet technology for solution phase XFEL experiments.IUCrJ · 2023Article
- 3D-printed sheet jet for stable megahertz liquid sample delivery at X-ray free-electron lasers.IUCrJ · 2023Article
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Authors and funding
6 authors.
Funding
Abstract
The metal centres in metalloenzymes and molecular catalysts are responsible for the rearrangement of atoms and electrons during complex chemical reactions, and they enable selective pathways of charge and spin transfer, bond breaking/making and the formation of new molecules. Mapping the electronic structural changes at the metal sites during the reactions gives a unique mechanistic insight that has been difficult to obtain to date. The development of X-ray free-electron lasers (XFELs) enables powerful new probes of electronic structure dynamics to advance our understanding of metalloenzymes. The ultrashort, intense and tunable XFEL pulses enable X-ray spectroscopic studies of metalloenzymes, molecular catalysts and chemical reactions, under functional conditions and in real time. In this Technical Review, we describe the current state of the art of X-ray spectroscopy studies at XFELs and highlight some new techniques currently under development. With more XFEL facilities starting operation and more in the planning or construction phase, new capabilities are expected, including high repetition rate, better XFEL pulse control and advanced instrumentation. For the first time, it will be possible to make real-time molecular movies of metalloenzymes and catalysts in solution, while chemical reactions are taking place.
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