Evidence map›Paper›PMID 34209000›Full record

ArticlePolymers2021

Enhancement of Flame Retardancy and Mechanical Properties of Polylactic Acid with a Biodegradable Fire-Retardant Filler System Based on Bamboo Charcoal.

Wenzhu Li, Liang Zhang, Weisheng Chai, Ningning Yin, Kate Semple, Lu Li, Wenbiao Zhang, Chunping Dai

Open access · goldAbstract read
In one paragraph

Article in Polymers, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
3.2field-weighted citation impact, top 8% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed, 42 citations in OpenAlex.

  1. TiPolymers · 2026
    Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 2 institutions in 2 countries.

Wenzhu LiZhejiang Provincial Collaborative Innovation Center for Bamboo Resources and High-Efficiency Utilization, College of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou 311300, China.
Liang ZhangZhejiang Provincial Collaborative Innovation Center for Bamboo Resources and High-Efficiency Utilization, College of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou 311300, China.
Weisheng ChaiZhejiang Provincial Collaborative Innovation Center for Bamboo Resources and High-Efficiency Utilization, College of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou 311300, China.
Ningning YinZhejiang Provincial Collaborative Innovation Center for Bamboo Resources and High-Efficiency Utilization, College of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou 311300, China.
Kate SempleDepartment of Wood Science, Faculty of Forestry, University of British Columbia, 2900-2424 Main Mall, Vancouver, BC V6T 1Z4, Canada.
Lu LiZhejiang Provincial Collaborative Innovation Center for Bamboo Resources and High-Efficiency Utilization, College of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou 311300, China.
Wenbiao ZhangZhejiang Provincial Collaborative Innovation Center for Bamboo Resources and High-Efficiency Utilization, College of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou 311300, China.
Chunping DaiDepartment of Wood Science, Faculty of Forestry, University of British Columbia, 2900-2424 Main Mall, Vancouver, BC V6T 1Z4, Canada.ORCID 0000-0003-1800-2437
Zhejiang A & F University · CNUniversity of British Columbia · CA

Funding

key development projects of Zhejiang Province 2018C02008Natural Sciences and Engineering Research Council of Canada NSERC
6 · The paper itself

Abstract

A cooperative flame-retardant system based on natural intumescent-grafted bamboo charcoal (BC) and chitosan (CS) was developed for polylactic acid (PLA) with improved flame retardancy and minimal decline in strength properties. Chitosan (CS) as an adhesion promoter improved the interfacial compatibility between graft-modified bamboo charcoal (BC-m) and PLA leading to enhanced tensile properties by 11.11% and 8.42%, respectively for tensile strength and modulus. At 3 wt.% CS and 30 wt.% BC-m, the crystallinity of the composite increased to 38.92%, or 43 times that of pure PLA (0.9%). CS promotes the reorganization of the internal crystal structure. Thermogravimetric analysis showed significantly improved material retention of PLA composites in nitrogen and air atmosphere. Residue rate for 5 wt.% CS and 30 wt.% BC-m was 29.42% which is 55.1% higher than the theoretical value of 18.97%. Flammability tests (limiting oxygen index-LOI and UL-94) indicated significantly improved flame retardancy and evidence of cooperation between CS and BC-m, with calculated cooperative effectiveness index(Ce) >1. From CONE tests, the peak heat release rate (pHRR) and total heat release (THR) were reduced by 26.9% and 30.5%, respectively, for 3% CS + 20% BC-m in PLA compared with adding 20% BC-m alone. Analysis of carbon residue morphology, chemical elements and structure suggest CS and BC-m form a more stable char containing pyrophosphate. This char provides heat insulation to inhibit complete polymer pyrolysis, resulting in improved flame retardancy of PLA composites. Optimal mix may be recommended at 20% BC-m + 3% CS to balance compatibility, composite strength properties and flame retardance.

Indexed as

bamboo charcoalchitosancooperative systemflame retardantpolylactic acid

Identifiers

PMID34209000
PMCPMC8271951
OpenAlexW3174774947

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.