ArticleAngewandte Chemie (International ed. in English)2021
Unravelling the Hydration Barrier of Lignin Oleate Nanoparticles for Acid- and Base-Catalyzed Functionalization in Dispersion State.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Impact of Type of Lignin, Alkaline and Lignosulfonate, on Release and Soil Adsorption of Methoxyfenozide Delivered with Lignin-ACS omega · 2026Article
- Upcycling birch bark suberin into versatile and recyclable thermosets.Green chemistry : an international journal and green chemistry resource : GC · 2026Article
- Engineering of Industrial Kraft Lignin: The Role of Esterification Methods in Lignin Nanoparticle Self-Assembly.Biomacromolecules · 2025Article
- Beta-Radiation-Resistant Anticorrosion Coatings Based on Lignin.Small science · 2025Article
- Lignin Dissolution and Direct Ultrasmall-Lignin-Nanoparticle Formation in Acidic and Alkaline Deep Eutectic Solvents: A Molecular-Level Insight.Angewandte Chemie (International ed. in English) · 2025Article
- Esterified Lignin Nanoparticles for Targeted Chemical Delivery in Plant Protection.ACS applied materials & interfaces · 2025Article
- Overcoming Challenges of Lignin Nanoparticles: Expanding Opportunities for Scalable and Multifunctional Nanomaterials.Accounts of chemical research · 2024Article
- Mechanically recyclable melt-spun fibers from lignin esters and iron oxide nanoparticles: towards circular lignin materials.Green chemistry : an international journal and green chemistry resource : GC · 2023Article
- Urushi as a Green Component for Thermally Curable Colloidal Lignin Particles and Hydrophobic Coatings.ACS macro letters · 2023Article
- Bioresource Upgrade for Sustainable Energy, Environment, and Biomedicine.Nano-micro letters · 2023Review
- Stabilized Lignin Nanoparticles for Versatile Hybrid and Functional Nanomaterials.Biomacromolecules · 2022Article
- Electrochemical Depolymerization of Lignin in a Biomass-based Solvent.ChemSusChem · 2022Article
- Fully Biobased Photothermal Films and Coatings for Indoor Ultraviolet Radiation and Heat Management.ACS applied materials & interfaces · 2022Article
- Catalyst-Free Synthesis of Lignin Vitrimers with Tunable Mechanical Properties: Circular Polymers and Recoverable Adhesives.ACS applied materials & interfaces · 2021Article
- Multifunctional lignin-based nanocomposites and nanohybrids.Green chemistry : an international journal and green chemistry resource : GC · 2021Review
- Unravelling the Hydration Barrier of Lignin Oleate Nanoparticles for Acid- and Base-Catalyzed Functionalization in Dispersion State.Angewandte Chemie (International ed. in English) · 2021Article
- High-Molecular-Weight Fractions of Spruce and Eucalyptus Lignin as a Perspective Nanoparticle-Based Platform for a Therapy Delivery in Liver Cancer.Frontiers in bioengineering and biotechnology · 2021Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Lignin nanoparticles (LNPs) are promising renewable nanomaterials with applications ranging from biomedicine to water purification. However, the instability of LNPs under acidic and basic conditions severely limits their functionalization for improved performance. Here, we show that controlling the degree of esterification can significantly improve the stability of lignin oleate nanoparticles (OLNPs) in acidic and basic aqueous dispersions. The high stability of OLNPs is attributed to the alkyl chains accumulated in the shell of the particle, which delays protonation/deprotonation of carboxylic acid and phenolic hydroxyl groups. Owing to the enhanced stability, acid- and base-catalyzed functionalization of OLNPs at pH 2.0 and pH 12.0 via oxirane ring-opening reactions were successfully performed. We also demonstrated these new functionalized particles as efficient pH-switchable dye adsorbents and anticorrosive particulate coatings.
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