ReviewChemical science2021
Capturing photochemical and photophysical transformations in iron complexes with ultrafast X-ray spectroscopy and scattering.
Review in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed, 60 citations in OpenAlex.
- Covalency control of photomagnetic relaxation in a manganese(II) photoswitch.Nature chemistry · 2026Article
- Pursuing Heteroleptic Ligand Design Principles for Photoactive Fe Complexes with Ultrafast X-ray Emission and Variable-Temperature Optical Spectroscopies.Journal of the American Chemical Society · 2026Article
- Metal-Centered Photoredox Catalysis using d6 Transition Metal-based Chromophores.Accounts of chemical research · 2026Article
- Ultrafast Spectroscopy with anACS physical chemistry Au · 2026Article
- Liquid jet capabilities for ultrafast chemistry at the SwissFEL Alvra instrument.Journal of synchrotron radiation · 2026Article
- Analysis strategies for time-resolved X-ray solution scattering at high repetition rate XFEL sources.Journal of synchrotron radiation · 2026Article
- Zinc(II) Monomeric, Dimeric, and Trimeric Photosensitizers with Microsecond-Lived Intra-ligand Charge Transfer Excited States Investigated through Time-Resolved Optical and X-Ray Spectroscopy.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Mixed gain detector configurations for time-resolved X-ray solution scattering.Journal of synchrotron radiation · 2025Article
- Capturing ultrafast molecular motions and lattice dynamics in spin crossover film using femtosecond diffraction methods.Nature communications · 2025Article
- Simulation of Ultrafast Excited-State Dynamics in Fe(II) Complexes: Assessment of Electronic Structure Descriptions.Journal of chemical theory and computation · 2025Article
- Structural Bifurcation in the High→Low-Spin and Low→High-Spin Phase Transitions Explains the Asymmetric Spin-Crossover in [FeLAngewandte Chemie (International ed. in English) · 2025Article
- Exploring the Influence of Approximations for Simulating Valence Excited X-ray Spectra.The journal of physical chemistry. A · 2024Article
- Resolving Photoinduced Femtosecond Three-Dimensional Solute-Solvent Dynamics through Surface Hopping Simulations.Journal of chemical theory and computation · 2024Article
- The Liquid Jet Endstation for Hard X-ray Scattering and Spectroscopy at the Linac Coherent Light Source.Molecules (Basel, Switzerland) · 2024Article
- A Survey of the Angular Distortion Landscape in the Coordination Geometries of High-Spin Iron(II) 2,6-Bis(pyrazolyl)pyridine Complexes.Inorganic chemistry · 2024Article
- Solvent-Dependent Structural Dynamics in the Ultrafast Photodissociation Reaction of Triiodide Observed with Time-Resolved X-ray Solution Scattering.Journal of the American Chemical Society · 2023Article
- Sensitivity of Kβ mainline X-ray emission to structural dynamics in iron photosensitizer.Physical chemistry chemical physics : PCCP · 2023Article
- Branching mechanism of photoswitching in an Fe(II) polypyridyl complex explained by full singlet-triplet-quintet dynamics.Communications chemistry · 2023Article
- Resolving Femtosecond Solvent Reorganization Dynamics in an Iron Complex by Nonadiabatic Dynamics Simulations.Journal of the American Chemical Society · 2022Article
- Review
Corrections and comments
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Authors and funding
1 author at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Light-driven chemical transformations provide a compelling approach to understanding chemical reactivity with the potential to use this understanding to advance solar energy and catalysis applications. Capturing the non-equilibrium trajectories of electronic excited states with precision, particularly for transition metal complexes, would provide a foundation for advancing both of these objectives. Of particular importance for 3d metal compounds is characterizing the population dynamics of charge-transfer (CT) and metal-centered (MC) electronic excited states and understanding how the inner coordination sphere structural dynamics mediate the interaction between these states. Recent advances in ultrafast X-ray laser science has enabled the electronic excited state dynamics in 3d metal complexes to be followed with unprecedented detail. This review will focus on simultaneous X-ray emission spectroscopy (XES) and X-ray solution scattering (XSS) studies of iron coordination and organometallic complexes. These simultaneous XES-XSS studies have provided detailed insight into the mechanism of light-induced spin crossover in iron coordination compounds, the interaction of CT and MC excited states in iron carbene photosensitizers, and the mechanism of Fe-S bond dissociation in cytochrome
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.