Evidence map›Paper›PMID 34191385›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021

Ni(II) Precatalysts Enable Thioetherification of (Hetero)Aryl Halides and Tosylates and Tandem C-S/C-N Couplings.

M Trinidad Martín, Mario Marín, Celia Maya, Auxiliadora Prieto, M Carmen Nicasio

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. C─S Bond Formation of Aryl Germanes.Angewandte Chemie (International ed. in English) · 2026
    Article
  2. ACS organic & inorganic Au · 2024
    Article
  3. Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

M Trinidad MartínDepartamento de Química Inorgánica, Universidad de Sevilla, Aptdo 1203, 41071, Sevilla, Spain.
Mario MarínDepartamento de Química Inorgánica, Universidad de Sevilla, Aptdo 1203, 41071, Sevilla, Spain.
Celia MayaInstituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Consejo Superior de Investigaciones Científicas (CSIC), Universidad de Sevilla, Avda. Américo Vespucio 49, 41092, Sevilla, Spain.
Auxiliadora PrietoLaboratorio de Catálisis Homogénea, Unidad Asociada al CSIC, CIQSO-Centro de Investigación en Química Sostenible and Departamento de Química, Campus de El Carmen s/n, Universidad de Huelva, 21007, Huelva, Spain.
M Carmen NicasioDepartamento de Química Inorgánica, Universidad de Sevilla, Aptdo 1203, 41071, Sevilla, Spain.ORCID http://orcid.org/0000-0002-6485-2953

Funding

Junta de Andalucía US-1262266Ministerio de Ciencia, Innovación y Universidades CTQ2017-82893-C2-2-R
6 · The paper itself

Abstract

Ni-catalyzed C-S cross-coupling reactions have received less attention compared with other C-heteroatom couplings. Most reported examples comprise the thioetherification of most reactive aryl iodides with aromatic thiols. The use of C-O electrophiles in this context is almost uncharted. Here, we describe that preformed Ni(II) precatalysts of the type NiCl(allyl)(PMe

Indexed as

ChloridesIodidesCatalysisSulfhydryl CompoundsChloridesIodidesSulfhydryl CompoundsC−S bond formationdual chemoselectivityNi catalysisphosphine complexestandem cross-couplings

Identifiers

PMID34191385
PMCPMC8456787

What OpenQuestion holds

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LicenceCC BY-NC-ND
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.