ArticleJournal of the American Chemical Society2021
Sequence Control from Mixtures: Switchable Polymerization Catalysis and Future Materials Applications.
Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 43 papers.
What it found
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The trial behind it
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Who cites it
43 citing papers in PubMed.
- Fluorine-Modulated Reactivity Enables One-Pot Kinetic Sequence Programming of Block Copolyesters.Polymers · 2026Article
- Chemically Recyclable Thermoplastic Elastomers: Preparation, Properties, and On-Demand Depolymerization.Precision chemistry · 2026Review
- Organocatalytic atom transfer radical polymerization with light and pH dual-gated regulation.Nature communications · 2026Article
- Function Meets Circularity: Metal-Ionomer Cross-Links Toughen and Recycle COMacromolecules · 2026Article
- Graph-Based Machine Learning Identifies Oxygenated Block Polymer Replacements for Conventional Plastics and Elastics.Journal of the American Chemical Society · 2026Article
- Controlled Polymerization Catalysis for the Synthesis of Degradable Amphiphilic Polycarbonates from COJournal of the American Chemical Society · 2026Article
- Multinuclear catalyst: An efficient tool for the synthesis of polyesters and polycarbonates by ring-opening polymerization.Fundamental research · 2026Review
- Block COACS macro letters · 2025Article
- (AB)Macromolecules · 2025Article
- Efficient Solution-Phase Synthesis of Sequence-Defined Oligourethanes with Precise Chirality Control.Macromolecular rapid communications · 2025Article
- Biodegradable and Chemically Recyclable Thermoplastic Elastomers Prepared by Ring-Opening Polymerization of Cyclic Monomers.Polymer science & technology (Washington, D.C.) · 2025Review
- Information propagation through enzyme-free catalytic templating of DNA dimerization with weak product inhibition.Nature chemistry · 2025Article
- Access to Microstructurally Complex Block Copolymers via Switchable Ring-Opening Polymerization of Cyclic Ester Mixtures.Macromolecules · 2025Article
- High-performance recyclable polymers enabled by stereo- and sequence-controlled polymerization.Nature chemistry · 2025Article
- High-Performance Recyclable Polyester Elastomers Through Transient Strain-Stiffening.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Using Differential Scanning Calorimetry to Accelerate Polymerization Catalysis: A Toolkit for Miniaturized and Automated Kinetics Measurements.ACS catalysis · 2025Article
- Binary Catalyst Manipulating the Sequences of Poly(ester-carbonate) Copolymers in Metal-Free Terpolymerization of Epoxide, Anhydride, and COPrecision chemistry · 2025Article
- Selective Copolymerization from Mixed Monomers of Phthalic Anhydride, Propylene Oxide and Lactide Using Nano-Sized Zinc Glutarate.Nanomaterials (Basel, Switzerland) · 2024Article
- Digital Light Processing to Afford High Resolution and Degradable COAngewandte Chemie (International ed. in English) · 2024Article
- Sustainable, Recyclable, and Bench-Stable Catalytic System for Synthesis of Poly(ester-Chem & bio engineering · 2024Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
There is an ever-increasing demand for higher-performing polymeric materials counterbalanced by the need for sustainability throughout the life cycle. Copolymers comprising ester, carbonate, or ether linkages could fulfill some of this demand as their monomer-polymer chemistry is closer to equilibrium, facilitating (bio)degradation and recycling; many monomers are or could be sourced from renewables or waste. Here, an efficient and broadly applicable route to make such copolymers is discussed, a form of switchable polymerization catalysis which exploits a single catalyst, switched between different catalytic cycles, to prepare block sequence selective copolymers from monomer mixtures. This perspective presents the principles of this catalysis, catalyst design criteria, the selectivity and structural copolymer characterization tools, and the properties of the resulting copolymers. Uses as thermoplastic elastomers, toughened plastics, adhesives, and self-assembled nanostructures, and for programmed degradation, among others, are discussed. The state-of-the-art research into both catalysis and products, as well as future challenges and directions, are presented.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.