ArticleProceedings of the National Academy of Sciences of the United States of America2021
Anthracene-induced formation of highly twisted metallacycle and its crystal structure and tunable assembly behaviors.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Phase transfer-driven formation of solid metal-organic materials with tunable optical and adsorption properties.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- π-Stacking among the Anthracenyl Groups of a Copper Complex Resulted in Doubling of Unit Cell Volume To Provide New Polymorphs.ACS omega · 2023Article
- Exposing Mechanisms for Defect Clearance in Supramolecular Self-Assembly: Palladium-Pyridine Coordination Revisited.Inorganic chemistry · 2023Article
- Entropy directs the self-assembly of supramolecular palladium coordination macrocycles and cages.Chemical science · 2022Article
- Beyond Platonic: How to Build Metal-Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes.Chemical reviews · 2022Review
- Metal-organic cycle-based multistage assemblies.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
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Authors and funding
12 authors.
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Abstract
Polycyclic aromatic hydrocarbons (PAHs) continue to attract increasing interest with respect to their applications as luminescent materials. The ordered structure of the metal-organic complex facilitates the selective integration of PAHs that can be tuned to function cooperatively. Here, a unique highly twisted anthracene-based organoplatinum metallacycle was prepared via coordination-driven self-assembly. Single-crystal X-ray diffraction analysis revealed that the metallacycle was twisted through the cooperation of strong π···π stacking interactions and steric hindrance between two anthracene-based ligands. Notably, the intramolecular twist and aggregation behavior introduced restrictions to the conformational change of anthracenes, which resulted in increased emission intensity of the metallacycle in solution. The emission behaviors and suprastructures based on the highly twisted metallacycle can be modulated by the introduction of different solvents. This study demonstrates that this metallacycle with highly twisted structure is a promising candidate for sensing and bioimaging applications.
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