ReviewChemical science2020
Phosphorus-ylides: powerful substituents for the stabilization of reactive main group compounds.
Review in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth-Ligand Cooperation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Isolable Phosphonioacetylides as Strong Neutral Carbon Donors with Variable Steric Demand and Tunable Donor Properties.Inorganic chemistry · 2026Article
- Nucleophilic Addition of Stabilized Phosphorus Ylides toMolecules (Basel, Switzerland) · 2026Article
- Rethinking carbanion chemistry from donor substituents to weakly coordinating carbanions.Nature reviews. Chemistry · 2025Review
- Isolation of a Cyclic Trinuclear Gold(I) Complex with Metalated Phosphorus Ylides: Synthesis and Structural Properties.Inorganic chemistry · 2024Article
- Reactivity of a Strictly T-Shaped Phosphine Ligated by an Acridane Derived NNN Pincer Ligand.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Probing the donor strength of yldiide ligands: synthesis, structure and reactivity of rhodium complexes with a PCChemical science · 2023Article
- From Stable PH-Ylides to α-Carbanionic Phosphines as Ligands for Zwitterionic Catalysts.Angewandte Chemie (International ed. in English) · 2022Article
- Nickel-catalysed diversification of phosphine ligands by formal substitution at phosphorus.Chemical science · 2022Article
- Ylide-Stabilized Phosphenium Cations: Impact of the Substitution Pattern on the Coordination Chemistry.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Accessing Cationic α-Silylated and α-Germylated Phosphorus Ylides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Single-Site and Cooperative Bond Activation Reactions with Ylide-Functionalized Tetrylenes: A Computational Study.European journal of inorganic chemistry · 2021Article
- Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl- and Amino-Substituted Metallated Ylide.ChemistryOpen · 2021Article
- Phosphorus-Containing Superbases: Recent Progress in the Chemistry of Electron-Abundant Phosphines and Phosphazenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Review
- A 2,2'-diphosphinotolane as a versatile precursor for the synthesis of P-ylidic mesoionic carbenesChemical science · 2021Article
- Synthesis of Low-Valent Dinuclear Group 14 Compounds with Element-Element Bonds by Transylidation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
Corrections and comments
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Authors and funding
3 authors.
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No grant is acknowledged in the PubMed record.
Abstract
Phosphorus ylides are 1,2-dipolar compounds with a negative charge on the carbon atom. This charge is stabilized by the neighbouring onium moiety, but can also be shifted towards other substituents thus making ylides strong π donor ligands and hence ideal substituents to stabilize reactive compounds such as cations and low-valent main group species. Furthermore, the donor strength and the steric properties can easily be tuned to meet different requirements for stabilizing reactive compounds and for tailoring the properties and reactivities of the main group element. Although the use of ylide substituents in main group chemistry is still in its infancy, the first examples of isolated compounds impressively demonstrate the potential of these ligands. This review summarizes the most important discoveries also in comparison to other substituents, thus outlining avenues for future research directions.
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