ReviewChemical science2020
Catalytic C-H to C-M (M = Al, Mg) bond transformations with heterometallic complexes.
Review in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
5 citing papers in PubMed.
- Cooperative activation of carbon-hydrogen bonds by heterobimetallic systems.Dalton transactions (Cambridge, England : 2003) · 2024Review
- Transition-Metal-Catalyzed C-H Bond Activation for the Formation of C-C Bonds in Complex Molecules.Chemical reviews · 2023Review
- C-H Activation of Inert Arenes using a Photochemically Activated Guanidinato-Magnesium(I) Compound.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- From mixed group 13 cations [M(AlCp*)Chemical science · 2022Article
- Diverse reactivity of an iron-aluminium complex with substituted pyridines.Chemical communications (Cambridge, England) · 2022Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
C-H functionalisation is one of the cornerstones of modern catalysis and remains a topic of contemporary interest due its high efficiency and atom-economy. Among these reactions, C-H borylation, that is the transformation of C-H to C-B bonds, has experienced a fast development because of the wide utility of organoboron reagents as synthetic intermediates. The mechanistic background is now well-understood and the role of transition metal boryl or σ-borane intermediates in this transformation is well documented. This mini-review focuses on efforts made by our group, and others, to establish palladium- and calcium-catalysed methods for C-H metalation employing heavier main group elements (M = Al, Mg). These are new catalytic reactions first accomplished in our group that we have termed C-H alumination and magnesiation respectively. Unusual heterometallic complexes have been identified as key on-cycle intermediates and their unique reactivity is discussed in the context of new catalytic pathways for C-H functionalisation. Hence, this mini-review summarises the recent progress in the area of C-H metalation reactions as well as the new opportunities that may arise from this concept.
Identifiers
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Registered trials
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