ReviewChemical science2020
Main group bimetallic partnerships for cooperative catalysis.
Review in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
25 citing papers in PubMed.
- Well-defined alkali metal catalysts for selective reduction of functionalized esters and carbonyl compoundsRSC advances · 2026Article
- Calcium Alkynyl(hydrido)zincates.Organometallics · 2026Article
- Manganese(II) and Magnesium(II) Analogies in Iridium Hydride Coordination Chemistry.Inorganic chemistry · 2026Article
- Multinuclear catalyst: An efficient tool for the synthesis of polyesters and polycarbonates by ring-opening polymerization.Fundamental research · 2026Review
- The fellowship of the Grignard: 21st century computational tools for hundred-year-old chemistry.Chemical science · 2025Review
- Boron, Aluminum, and Gallium Fluorides as Catalysts for the Defluorofunctionalization of Electron-Deficient Arenes: The Role of NaBArInorganic chemistry · 2025Article
- Room-Temperature Intermolecular Hydroamination of Vinylarenes Catalyzed by Alkali-Metal Ferrate Complexes.ACS organic & inorganic Au · 2025Article
- Synergic Catalysis: the Importance of Intermetallic Separation in Co(III)K(I) Catalysts for Ring Opening Copolymerizations.Journal of the American Chemical Society · 2024Article
- Application of Bis(amido)alkyl Magnesiates toward the Synthesis of Molecular Rubidium and Cesium Hydrido-magnesiates.Organometallics · 2024Article
- Cooperative activation of carbon-hydrogen bonds by heterobimetallic systems.Dalton transactions (Cambridge, England : 2003) · 2024Review
- Anions featuring an aluminium-silicon core with alumanyl silanide and aluminata-silene characteristics.Nature chemistry · 2023Article
- Understanding catalytic synergy in dinuclear polymerization catalysts for sustainable polymers.Nature communications · 2023Article
- Snapshots of sequential polyphosphide rearrangement upon metallatetrylene addition.Chemical science · 2023Article
- Synthesis, Characterization, and Structural Analysis ofInorganic chemistry · 2022Article
- C-H Activation of Inert Arenes using a Photochemically Activated Guanidinato-Magnesium(I) Compound.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Article
- Small molecule activation with bimetallic systems: a landscape of cooperative reactivity.Chemical communications (Cambridge, England) · 2022Review
- Hydrocarbon Soluble Alkali-Metal-Aluminium Hydride Surrog[ATES].Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Heavy Alkali Metal Manganate Complexes: Synthesis, Structures and Solvent-Induced Dissociation Effects.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Binding, Release and Functionalization of Intact Pnictogen Tetrahedra Coordinated to Dicopper Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Over the past decade s-block metal catalysis has undergone a transformation from being an esoteric curiosity to a well-established and consolidated field towards sustainable synthesis. Earth-abundant metals such as Ca, Mg, and Al have shown eye-opening catalytic performances in key catalytic processes such as hydrosilylation, hydroamination or alkene polymerization. In parallel to these studies, s-block mixed-metal reagents have also been attracting widespread interest from scientists. These bimetallic reagents effect many cornerstone organic transformations, often providing enhanced reactivities and better chemo- and regioselectivities than conventional monometallic reagents. Despite a significant number of synthetic advances to date, most efforts have focused primarily on stoichiometric transformations. Merging these two exciting areas of research, this Perspective Article provides an overview on the emerging concept of s/p-block cooperative catalysis. Showcasing recent contributions from several research groups across the world, the untapped potential that these systems can offer in catalytic transformations is discussed with special emphasis placed on how synergistic effects can operate and the special roles played by each metal in these transformations. Advancing the understanding of the ground rules of s-block cooperative catalysis, the application of these bimetalic systems in a critical selection of catalytic transformations encompassing hydroamination, cyclisation, hydroboration to C-C bond forming processes are presented as well as their uses in important polymerization reactions.
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Registered trials
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