ArticleChemical science2020
Born-Oppenheimer approximation in optical cavities: from success to breakdown.
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Disentangling the absorption lineshape of methylene blue for nanocavity strong coupling.Nanophotonics (Berlin, Germany) · 2025Article
- Understanding Polaritonic Chemistry from Ab Initio Quantum Electrodynamics.Chemical reviews · 2023Review
- The role of dephasing for dark state coupling in a molecular Tavis-Cummings model.The Journal of chemical physics · 2023Article
- Activating cavity by electrons.Communications physics · 2023Article
- Theoretical Challenges in Polaritonic Chemistry.ACS photonics · 2022Review
- Impact of cavity on interatomic Coulombic decay.Nature communications · 2021Article
- Polaritonic Chemistry: Collective Strong Coupling Implies Strong Local Modification of Chemical Properties.The journal of physical chemistry letters · 2021Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The coupling of a molecule and a cavity induces nonadiabaticity in the molecule which makes the description of its dynamics complicated. For polyatomic molecules, reduced-dimensional models and the use of the Born-Oppenheimer approximation (BOA) may remedy the situation. It is demonstrated that contrary to expectation, BOA may even fail in a one-dimensional model and is generally expected to fail in two- or more-dimensional models due to the appearance of conical intersections induced by the cavity.
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Registered trials
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