ArticleChemical science2021
A protecting group strategy to access stable lacunary polyoxomolybdates for introducing multinuclear metal clusters.
Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Tuning Uranium Redox Chemistry in Asymmetric Polyoxometalate Complexes: Access to U(IV), U(V), and Transient U(VI).Inorganic chemistry · 2026Article
- Unique Structural Features of Polyoxometalates for Efficient Alkaline Hydrogen-Evolution Reaction.ChemSusChem · 2026Review
- Recent Advances in Polyoxometalate‒Metal Nanocluster Hybrids.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Review
- Molecular hybrids of trivacant lacunary polyoxomolybdate and multidentate organic ligands.Chemical science · 2023Article
- Coupled reaction equilibria enable the light-driven formation of metal-functionalized molecular vanadium oxides.Nature communications · 2023Article
- Recent Advances of Ti/Zr-Substituted Polyoxometalates: From Structural Diversity to Functional Applications.Molecules (Basel, Switzerland) · 2022Review
- A photo-switchable molecular capsule: sequential photoinduced processes.Chemical science · 2022Article
- Variable control of the electronic states of a silver nanoclusterChemical science · 2022Article
- Roles of Organic Fragments in Redirecting Crystal/Molecular Structures of Inorganic-Organic Hybrids Based on Lacunary Keggin-Type Polyoxometalates.Molecules (Basel, Switzerland) · 2021Review
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Although metal-containing polyoxomolybdates (molybdenum oxide clusters) exhibit outstanding catalytic properties, their precise synthetic method has not yet been developed. This is mainly because the very low stability of the multivacant lacunary polyoxomolybdates limited their use as synthetic precursors. Here, we present a "protecting group strategy" in polyoxometalate synthesis and successfully develop an efficient method for synthesising multinuclear metal-containing polyoxomolybdates using pyridine as a protecting group for unstable trivacant lacunary Keggin-type polyoxomolybdate [PMo
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