ArticleChemical science2020
Molecular and supported Ti(iii)-alkyls: efficient ethylene polymerization driven by the π-character of metal-carbon bonds and back donation from a singly occupied molecular orbital.
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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Who cites it
7 citing papers in PubMed.
- Mechanistic Pathways and Product Selectivity in Pyrolysis of PE, PP and PVC: A Foundation for Applied Chemistry in Europe.Molecules (Basel, Switzerland) · 2026Review
- Optimized shaped pulses for a 2D single-frequency technique for refocusing (SIFTER).Magnetic resonance (Gottingen, Germany) · 2025Article
- Increased sensitivity in electron-nuclear double resonance spectroscopy with chirped radiofrequency pulses.Magnetic resonance (Gottingen, Germany) · 2025Article
- Geometry and electronic structure of Yb(III)[CH(SiMePhysical chemistry chemical physics : PCCP · 2024Article
- Review
- AssigningChemical science · 2023Article
- Union carbide polymerization catalysts: from uncovering active site structures to designing molecularly-defined analogs.Chemical science · 2022Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
While Ti(iii) alkyl species are the proposed active sites in Ziegler-Natta ethylene polymerization catalysts, the corresponding well-defined homogeneous catalysts are not known. We report that well-defined neutral β-diiminato Ti(iii) alkyl species, namely [Ti(nacnac)(CH
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Registered trials
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