ArticleChemical science2021
Selective adsorptive separation of cyclohexane over benzene using thienothiophene cages.
Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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Who cites it
19 citing papers in PubMed.
- Guest-dependent solid-state superstructure plasticity and its application to adsorptive benzene sieving.Chemical science · 2026Article
- Supramolecular liquid-liquid extraction enabled by CyRSC advances · 2026Article
- Nonporous Adaptive Crystals Based on Pillararene/Calixarene-Inspired Novel Macrocyclic Arenes.Exploration (Beijing, China) · 2025Review
- Formation of a PdJACS Au · 2025Article
- Kinetic Trapping of Rylene Diimide Covalent Organic Cages.The Journal of organic chemistry · 2025Article
- Guest-Induced Conformational Transformations in Tiara[5]arene Crystals: A Pathway for Molecular Sieving.JACS Au · 2024Article
- Synergy of pore size and silanols in an -SVR-type zeolite for efficient dynamic benzene/cyclohexane separation.Nature communications · 2024Article
- Adsorptive Separation of Methylfuran and Dimethylfuran by a Robust Porous Organic Cage.Chem & bio engineering · 2024Article
- Complete separation of benzene-cyclohexene-cyclohexane mixtures via temperature-dependent molecular sieving by a flexible chain-like coordination polymer.Nature communications · 2024Article
- A Diverse Array of Large Capsules Transform in Response to Stimuli.Journal of the American Chemical Society · 2023Article
- A Benzothiadiazole-Based Self-Assembled Cage for Cadmium Detection.Molecules (Basel, Switzerland) · 2023Article
- Unravelling Structural Dynamics, Supramolecular Behavior, and Chiroptical Properties of Enantiomerically Pure Macrocyclic Tertiary Ureas and Thioureas.The Journal of organic chemistry · 2023Article
- A Porous Polyaromatic Solid for Vapor Adsorption of Xylene with High Efficiency, Selectivity, and Reusability.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Selective separation of planar and non-planar hydrocarbons using an aqueous PdChemical science · 2022Article
- Adsorptive separation ofRSC advances · 2022Article
- Cagearenes: synthesis, characterization, and application for programmed vapour release.Chemical science · 2022Article
- Chiral proline-substituted porous organic cages in asymmetric organocatalysis.Chemical science · 2022Article
- Pillar[3]trianglamines: deeper cavity triangular macrocycles for selective hexene isomer separation.Chemical science · 2022Article
- Tuning the porosity of triangular supramolecular adsorbents for superior haloalkane isomer separations.Chemical science · 2021Article
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Authors and funding
7 authors.
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Abstract
The selective separation of benzene (Bz) and cyclohexane (Cy) is one of the most challenging chemical separations in the petrochemical and oil industries. In this work, we report an environmentally friendly and energy saving approach to separate Cy over Bz using thienothiophene cages (ThT-cages) with adaptive porosity. Interestingly, cyclohexane was readily captured selectively from an equimolar benzene/cyclohexane mixture with a purity of 94%. This high selectivity arises from the C-H⋯S, C-H⋯π and C-H⋯N interactions between Cy and the thienothiophene ligand. Reversible transformation between the nonporous guest-free structure and the host-guest assembly, endows this system with excellent recyclability with minimal energy requirements.
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