Evidence map›Paper›PMID 34163762›Full record

ArticleChemical science2021

Porous shape-persistent rylene imine cages with tunable optoelectronic properties and delayed fluorescence.

Hsin-Hua Huang, Kyung Seob Song, Alessandro Prescimone, Alexander Aster, Gabriel Cohen, Rajesh Mannancherry, Eric Vauthey, Ali Coskun, Tomáš Šolomek

Abstract read
In one paragraph

Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.

0numbers the graph read from it
0cells of the map it votes in
11citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

11 citing papers in PubMed.

  1. Article
  2. Porous Organic Cages for COAngewandte Chemie (International ed. in English) · 2026
    Review
  3. Kinetic Trapping of Rylene Diimide Covalent Organic Cages.The Journal of organic chemistry · 2025
    Article
  4. Article
  5. Article
  6. Bimolecular photoinduced symmetry-breaking charge separation of perylene in solution.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2024
    Article
  7. Article
  8. Porous organic polymers for COChemical Society reviews · 2022
    Review
  9. COChemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Article
  10. Review
  11. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Hsin-Hua HuangDepartment of Chemistry, University of Basel St. Johanns-Ring 19 CH-4056 Basel Switzerland tomas.solomek@unibas.ch.ORCID https://orcid.org/0000-0001-6901-1283
Kyung Seob SongDepartment of Chemistry, University of Fribourg Chemin Du Musée 9 1700 Fribourg Switzerland ali.coskun@unifr.ch.
Alessandro PrescimoneDepartment of Chemistry, University of Basel St. Johanns-Ring 19 CH-4056 Basel Switzerland tomas.solomek@unibas.ch.ORCID https://orcid.org/0000-0002-3631-5210
Alexander AsterDepartment of Physical Chemistry, University of Geneva CH-1211 Geneva Switzerland.
Gabriel CohenDepartment of Physical Chemistry, University of Geneva CH-1211 Geneva Switzerland.
Rajesh MannancherryDepartment of Chemistry, University of Basel St. Johanns-Ring 19 CH-4056 Basel Switzerland tomas.solomek@unibas.ch.ORCID https://orcid.org/0000-0003-4501-8573
Eric VautheyDepartment of Physical Chemistry, University of Geneva CH-1211 Geneva Switzerland.ORCID https://orcid.org/0000-0002-9580-9683
Ali CoskunDepartment of Chemistry, University of Fribourg Chemin Du Musée 9 1700 Fribourg Switzerland ali.coskun@unifr.ch.ORCID https://orcid.org/0000-0002-4760-1546
Tomáš ŠolomekDepartment of Chemistry, University of Basel St. Johanns-Ring 19 CH-4056 Basel Switzerland tomas.solomek@unibas.ch.ORCID https://orcid.org/0000-0003-0013-4116

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A simultaneous combination of porosity and tunable optoelectronic properties, common in covalent organic frameworks, is rare in shape-persistent organic cages. Yet, organic cages offer important molecular advantages such as solubility and modularity. Herein, we report the synthesis of a series of chiral imine organic cages with three built-in rylene units by means of dynamic imine chemistry and we investigate their textural and optoelectronic properties. Thereby we demonstrate that the synthesized rylene cages can be reversibly reduced at accessible potentials, absorb from UV up to green light, are porous, and preferentially adsorb CO

Identifiers

PMID34163762
PMCPMC8179562

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.