ArticleChemical science2021
Mechanochemical generation of acid-degradable poly(enol ether)s.
Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 13 papers.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
13 citing papers in PubMed.
- Precise Structural Design for Chemically Recyclable Polymers.Precision chemistry · 2026Review
- Boosting Natural Rubber Performance by Backbone Rigid Functionalization.Angewandte Chemie (International ed. in English) · 2026Article
- Mechanically Triggered Chemical Recyclable Polyethylene-Like Materials.Angewandte Chemie (International ed. in English) · 2026Article
- Cycloreversion-enhanced toughness and degradability in mechanophore-embedded end-linked polymer networks.Nature communications · 2026Article
- Logic-Gated Release of a Dual Payload from a β-Lactam Mechanophore with a Rotaxane Actuator.Angewandte Chemie (International ed. in English) · 2025Article
- Two dimensional MoSNature communications · 2025Article
- Mechanically triggered on-demand degradation of polymers synthesized by radical polymerizations.Nature chemistry · 2024Article
- Tribochemical nanolithography: selective mechanochemical removal of photocleavable nitrophenyl protecting groups with 23 nm resolution at speeds of up to 1 mm sChemical science · 2023Article
- Mechanochemically accessing a challenging-to-synthesize depolymerizable polymer.Nature communications · 2023Article
- Mechanoluminescent Materials Enable Mechanochemically Controlled Atom Transfer Radical Polymerization and Polymer Mechanotransduction.Research (Washington, D.C.) · 2023Article
- Article
- Force ahead: Emerging Applications and Opportunities of Polymer Mechanochemistry.ACS polymers Au · 2022Article
- Synthesis of degradable and chemically recyclable polymers using 4,4-disubstituted five-membered cyclic ketene hemiacetal ester (CKHE) monomers.Chemical science · 2021Article
Corrections and comments
- Erratum issued
Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In an effort to develop polymers that can undergo extensive backbone degradation in response to mechanical stress, we report a polymer system that is hydrolytically stable but unmasks easily hydrolysable enol ether backbone linkages when force is applied. These polymers were synthesized by ring-opening metathesis polymerization (ROMP) of a novel mechanophore monomer consisting of cyclic ether fused bicyclohexene. Hydrogenation of the resulting polymers led to significantly enhanced thermal stability (
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.