ArticleChemical science2021
Photoredox catalysis on unactivated substrates with strongly reducing iridium photosensitizers.
Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 32 papers.
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Who cites it
32 citing papers in PubMed, 106 citations in OpenAlex.
- Photocatalytic Cross-Coupling of Phenols and Heteroaryl Halides With Machine Learning-Guided Reaction Prediction.Angewandte Chemie (International ed. in English) · 2026Article
- Homomolecular Photon Upconversion in a Perylene-Decorated Iron(III) Complex.Journal of the American Chemical Society · 2025Article
- Structural Control of Metal-Centered Excited States in Cobalt(III) Complexes via Bite Angle and π-π Interactions.Journal of the American Chemical Society · 2025Article
- Design of aminoanthraquinone-based heterogeneous photocatalysts for visible-light-driven reactions and antibacterial applications.RSC advances · 2025Article
- Nickel-Catalyzed Hydro- and Deutero-dehalogenations of (Hetero)Aryl Halides under Aqueous Micellar Catalysis Conditions.ChemSusChem · 2025Article
- Tuning the Efficiency of Iridium(III) Complexes for Energy Transfer (EnT) Catalysis through Ligand Design.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Co-Catalytic Coupling of Alkyl Halides and Alkenes: the Curious Role of Lutidine.Journal of the American Chemical Society · 2025Article
- Artificial Photosynthases: Single-Chain Nanoparticles with Manifold Visible-Light Photocatalytic Activity for Challenging "in Water" Organic Reactions.Journal of the American Chemical Society · 2024Article
- Iron(III) Carbene Complexes with Tunable Excited State Energies for Photoredox and Upconversion.Journal of the American Chemical Society · 2024Article
- Improved transition metal photosensitizers to drive advances in photocatalysis.Chemical science · 2023Review
- Photoredox-active Cr(0) luminophores featuring photophysical properties competitive with Ru(II) and Os(II) complexes.Nature chemistry · 2023Article
- Exploiting Visible Light Triggered Formation ofOrganic letters · 2023Article
- Photo-Induced, Phenylhydrazine-Promoted Transition-Metal-Free Dehalogenation of Aryl Fluorides, Chlorides, Bromides, and Iodides.Molecules (Basel, Switzerland) · 2023Article
- Reductive photoredox transformations of carbonyl derivatives enabled by strongly reducing photosensitizers.Chemical science · 2023Article
- Metal-free reduction of CONature chemistry · 2023Article
- Photocatalytic Regeneration of a Nicotinamide Adenine Nucleotide Mimic with Water-Soluble Iridium(III) Complexes.Inorganic chemistry · 2023Article
- Unexplored Facet of Pincer Ligands: Super-Reductant Behavior Applied to Transition-Metal-Free Catalysis.JACS Au · 2023Article
- Light-Driven Hydrodefluorination of Electron-Rich Aryl Fluorides by an Anionic Rhodium-Gallium Photoredox Catalyst.Angewandte Chemie (International ed. in English) · 2022Article
- Tuning Deazaflavins Towards Highly Potent Reducing Photocatalysts Guided by Mechanistic Understanding - Enhancement of the Key Step by the Internal Heavy Atom Effect.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Shedding Light on the Oxidizing Properties of Spin-Flip Excited States in a CrJournal of the American Chemical Society · 2022Article
Corrections and comments
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Authors and funding
6 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Photoredox catalysis has emerged as a powerful strategy in synthetic organic chemistry, but substrates that are difficult to reduce either require complex reaction conditions or are not amenable at all to photoredox transformations. In this work, we show that strong bis-cyclometalated iridium photoreductants with electron-rich β-diketiminate (NacNac) ancillary ligands enable high-yielding photoredox transformations of challenging substrates with very simple reaction conditions that require only a single sacrificial reagent. Using blue or green visible-light activation we demonstrate a variety of reactions, which include hydrodehalogenation, cyclization, intramolecular radical addition, and prenylation
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.