Evidence map›Paper›PMID 34163667›Full record

ArticleChemical science2021

The electronic structure and deexcitation pathways of an isolated metalloporphyrin ion resolved by metal L-edge spectroscopy.

Kaja Schubert, Meiyuan Guo, Kaan Atak, Simon Dörner, Christine Bülow, Bernd von Issendorff, Stephan Klumpp, J Tobias Lau, Piter S Miedema, Thomas Schlathölter and 6 more

Abstract read
In one paragraph

Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

16 authors.

Kaja SchubertDeutsches Elektronen-Synchrotron DESY 22607 Hamburg Germany kaja.schubert@desy.de sadia.bari@desy.de.ORCID https://orcid.org/0000-0002-6362-4262
Meiyuan GuoDivision of Chemical Physics, Chemical Center, Lund University SE-221 00 Lund Sweden.ORCID https://orcid.org/0000-0003-2474-6264
Kaan AtakDeutsches Elektronen-Synchrotron DESY 22607 Hamburg Germany kaja.schubert@desy.de sadia.bari@desy.de.
Simon DörnerDeutsches Elektronen-Synchrotron DESY 22607 Hamburg Germany kaja.schubert@desy.de sadia.bari@desy.de.ORCID https://orcid.org/0000-0001-9628-0147
Christine BülowAbteilung für Hochempfindliche Röntgenspektroskopie, Helmholtz-Zentrum Berlin für Materialien und Energie 12489 Berlin Germany.
Bernd von IssendorffPhysikalisches Institut, Albert-Ludwigs-Universität Freiburg 79104 Freiburg Germany.
Stephan KlumppDeutsches Elektronen-Synchrotron DESY 22607 Hamburg Germany kaja.schubert@desy.de sadia.bari@desy.de.ORCID https://orcid.org/0000-0002-3222-8195
J Tobias LauAbteilung für Hochempfindliche Röntgenspektroskopie, Helmholtz-Zentrum Berlin für Materialien und Energie 12489 Berlin Germany.ORCID https://orcid.org/0000-0003-0976-6902
Piter S MiedemaDeutsches Elektronen-Synchrotron DESY 22607 Hamburg Germany kaja.schubert@desy.de sadia.bari@desy.de.ORCID https://orcid.org/0000-0003-1959-3216
Thomas SchlathölterZernike Institute for Advanced Materials, University of Groningen 9747 AG Groningen The Netherlands.ORCID https://orcid.org/0000-0001-9923-172X
Simone TechertDeutsches Elektronen-Synchrotron DESY 22607 Hamburg Germany kaja.schubert@desy.de sadia.bari@desy.de.ORCID https://orcid.org/0000-0002-7549-7651
Martin TimmAbteilung für Hochempfindliche Röntgenspektroskopie, Helmholtz-Zentrum Berlin für Materialien und Energie 12489 Berlin Germany.ORCID https://orcid.org/0000-0003-4901-203X
Xin WangZernike Institute for Advanced Materials, University of Groningen 9747 AG Groningen The Netherlands.
Vicente Zamudio-BayerAbteilung für Hochempfindliche Röntgenspektroskopie, Helmholtz-Zentrum Berlin für Materialien und Energie 12489 Berlin Germany.ORCID https://orcid.org/0000-0002-4038-0584
Lucas SchwobDeutsches Elektronen-Synchrotron DESY 22607 Hamburg Germany kaja.schubert@desy.de sadia.bari@desy.de.ORCID https://orcid.org/0000-0002-4274-365X
Sadia BariDeutsches Elektronen-Synchrotron DESY 22607 Hamburg Germany kaja.schubert@desy.de sadia.bari@desy.de.ORCID https://orcid.org/0000-0003-3985-2051

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The local electronic structure of the metal-active site and the deexcitation pathways of metalloporphyrins are crucial for numerous applications but difficult to access by commonly employed techniques. Here, we applied near-edge X-ray absorption mass spectrometry and quantum-mechanical restricted active space calculations to investigate the electronic structure of the metal-active site of the isolated cobalt(iii) protoporphyrin IX cation (CoPPIX

Identifiers

PMID34163667
PMCPMC8179464

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.