ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
N-Heterocyclic Iod(az)olium Salts - Potent Halogen-Bond Donors in Organocatalysis.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Spirosilanes Activate Gold(I)-Catalysts in Cycloisomerization and Intermolecular Reactions.Angewandte Chemie (International ed. in English) · 2026Article
- Highly Enantioselective Organocatalysis with Bidentate Halogen Bond Donors.Angewandte Chemie (International ed. in English) · 2025Article
- Evaluating the halogen bonding strength of a iodoloisoxazolium(III) salt.Beilstein journal of organic chemistry · 2024Article
- Halogen Bond-Involving Self-Assembly of Iodonium Carboxylates: Adding a Dimension to Supramolecular Architecture.International journal of molecular sciences · 2023Article
- Recent Progress in Cyclic Aryliodonium Chemistry: Syntheses and Applications.Chemical reviews · 2023Review
- Synthesis and reactivity of azole-based iodazinium salts.Beilstein journal of organic chemistry · 2023Article
- N-Heterocyclic Iod(az)olium Salts - Potent Halogen-Bond Donors in Organocatalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
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4 authors.
Funding
Abstract
This article describes the application of N-heterocyclic iod(az)olium salts (NHISs) as highly reactive organocatalysts. A variety of mono- and dicationic NHISs are described and utilized as potent XB-donors in halogen-bond catalysis. They were benchmarked in seven diverse test reactions in which the activation of carbon- and metal-chloride bonds as well as carbonyl and nitro groups was achieved. N-methylated dicationic NHISs rendered the highest reactivity in all investigated catalytic applications with reactivities even higher than all previously described monodentate XB-donors based on iodine(I) and (III) and the strong Lewis acid BF
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