ArticleJournal of the American Chemical Society2021
Carborane Stabilized "19-Electron" Molybdenum Metalloradical.
Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
7 citing papers in PubMed.
- Metal-metalChemical science · 2026Article
- Directing structural transformation in gold(i)-carborane nanoclusters to unlock ultrafast hypergolic ignition.Chemical science · 2026Article
- Carboranes without Cage Carbons:Journal of the American Chemical Society · 2025Article
- Formation and reactivity of a unique M⋯C-H interaction stabilized by carborane cages.Chemical science · 2024Article
- Arene C-H borylation strategy enabled by a non-classical boron cluster-based electrophile.Nature communications · 2023Article
- Geometrically constrained square pyramidal phosphoranide.Chemical science · 2022Article
- Metal-catalyzed B-H acylmethylation of pyridylcarboranes: access to carborane-fused indoliziniums and quinoliziniums.Chemical science · 2021Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Paramagnetic metal complexes gained a lot of attention due to their participation in a number of important chemical reactions. In most cases, these complexes are dominated by 17-e metalloradicals that are associatively activated with highly reactive paramagnetic 19-e species. Molybdenum paramagnetic complexes are among the most investigated ones. While some examples of persistent 17-e Mo-centered radicals have been reported, in contrast, 19-e Mo-centered radicals are illusive species and as such could rarely be detected. In this work, the photodissociation of the [Cp(CO)
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Registered trials
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