Evidence map›Paper›PMID 34159971›Full record

ArticleChemical communications (Cambridge, England)2021

Complete deconstruction of SF

Daniel J Sheldon, Mark R Crimmin

Open access · hybridAbstract read
In one paragraph

Article in Chemical communications (Cambridge, England), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.

0numbers the graph read from it
0cells of the map it votes in
11citing papers in PubMed
1.8field-weighted citation impact, top 15% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

11 citing papers in PubMed, 31 citations in OpenAlex.

  1. Article
  2. Bimetallic Activation of SFInorganic chemistry · 2025
    Article
  3. Routes to Pt Derivatives of High-Valent Sulfur Oxofluorides S(═O)Angewandte Chemie (International ed. in English) · 2025
    Article
  4. Article
  5. Anionic Reactions Degrading SFRapid communications in mass spectrometry : RCM · 2025
    Article
  6. Activation and Catalytic Degradation of SFJournal of the American Chemical Society · 2024
    Article
  7. Article
  8. Article
  9. Review
  10. Article
  11. Fluorination Reactions at a Platinum Carbene Complex: Reaction Routes to SFChemistry (Weinheim an der Bergstrasse, Germany) · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors at 1 institution in 2 countries.

Daniel J SheldonMolecular Sciences Research Hub, Department of Chemistry, Imperial College London, London, W12 0BZ, UK. m.crimmin@imperial.ac.uk.ORCID http://orcid.org/0000-0002-2059-776X
Mark R CrimminMolecular Sciences Research Hub, Department of Chemistry, Imperial College London, London, W12 0BZ, UK. m.crimmin@imperial.ac.uk.ORCID http://orcid.org/0000-0002-9339-9182
Transnational Press London

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The room-temperature activation of SF6, a potent greenhouse gas, is reported using a monovalent aluminium(i) reagent to form well-defined aluminium(iii) fluoride and aluminium(iii) sulfide products. New reactions have been developed to utilise the aluminium(iii) fluoride and aluminium(iii) sulfide as a nucleophilic source of F- and S2- for a range of electrophiles. The overall reaction sequence results in the net transfer of fluorine or sulfur atoms from an environmentally detrimental gas to useful organic products.

Identifiers

PMID34159971
PMCPMC8291285
OpenAlexW3166248083

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.