ArticleNature communications2021
Selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed, 52 citations in OpenAlex.
- Dual Photoredox/Cobalt Catalysis Enabled Regiospecific Markovnikov Hydroboration of Unactivated Mono-, Di-, and Trisubstituted Alkenes.Nature communications · 2026Article
- Regiodivergent Cyclotrimerization of Alkynes: Switchable Selectivities by Iron and Nickel Catalysts.Precision chemistry · 2026Article
- Markovnikov-Selective Hydroboration of Aryl Alkenes Catalyzed by Quaternary Ammonium Salts.Journal of the American Chemical Society · 2025Article
- Alkyne Dihydroboration viaJournal of the American Chemical Society · 2025Article
- Regioselective Multiboration and Hydroboration of Alkenes and Alkynes Enabled by a Platinum Single-Atom Catalyst.ACS catalysis · 2025Article
- Nickel-catalyzed C(spCommunications chemistry · 2025Article
- Designer topological-single-atom catalysts with site-specific selectivity.Nature communications · 2025Article
- The current utility and future potential of multiborylated alkanes.Nature reviews. Chemistry · 2024Review
- Divergent catalytic behaviors of assembled organogold(i) clusters derived from enyne cyclization.Chemical science · 2024Article
- Copper-Metallized Porous N-Heterocyclic Carbene Ligand Polymer-Catalyzed Regio- and Stereoselective 1,2-Carboboration of Alkynes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Homoleptic octahedral CoRSC advances · 2023Article
- Atomically Precise Metal Nanoclusters as Single Electron Transferers for Hydroborylation.Precision chemistry · 2023Article
- Mechanistic study of homoleptic trisamidolanthanide-catalyzed aldehyde and ketone hydroboration. Chemically non-innocent ligand participation.Chemical science · 2023Article
- Pyridine dicarbanion-bonded AgChemical science · 2022Article
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 2 countries.
Funding
Abstract
Homogeneous earth-abundant metal catalysis based on well-defined molecular complexes has achieved great advance in synthetic methodologies. However, sophisticated ligand, hazardous activator and multistep synthesis starting from base metal salts are generally required for the generation of active molecular catalysts, which may hinder their broad application in large scale organic synthesis. Therefore, the development of metal cluster catalysts formed in situ from simple earth-abundant metal salts is of importance for the practical utilization of base metal resource, yet it is still in its infancy. Herein, a mixture of catalytic amounts of cobalt (II) iodide and potassium tert-butoxide is discovered to be highly active for selective hydroboration of vinylarenes and dihydroboration of nitriles, affording a good yield of diversified hydroboration products that without isolation can readily undergo further one pot transformations. It should be highlighted that the alkoxide-pinacolborane combination acts as an efficient activation strategy to activate cobalt (II) iodide for the generation of metastable heterotopic cobalt catalysts in situ, which is proposed to be catalytically active species.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.