Evidence map›Paper›PMID 34151557›Full record

ArticleOrganic letters2021

Modular Synthesis of Alkenyl Sulfamates and β-Ketosulfonamides via Sulfur(VI) Fluoride Exchange (SuFEx) Click Chemistry and Photomediated 1,3-Rearrangement.

Felipe Cesar Sousa E Silva, Katarzyna Doktor, Quentin Michaudel

Open access · greenAbstract read
In one paragraph

Article in Organic letters, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
2.2field-weighted citation impact, top 13% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 26 citations in OpenAlex.

  1. Article
  2. Bifunctional Aziridines from Photochemically Generated FSOAngewandte Chemie (International ed. in English) · 2026
    Article
  3. Review
  4. Article
  5. Phosphite mediated molecular editingChemical science · 2025
    Article
  6. Article
  7. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors at 1 institution in 1 country.

Felipe Cesar Sousa E SilvaDepartment of Chemistry, Texas A&M University, College Station, Texas 77843, United States.
Katarzyna DoktorDepartment of Chemistry, Texas A&M University, College Station, Texas 77843, United States.
Quentin MichaudelDepartment of Chemistry, Texas A&M University, College Station, Texas 77843, United States.ORCID 0000-0002-1791-9174
Texas A&M University · US

Funding

Primary Amines as Versatile Precursors for the Synthesis of Bioactive Molecules and Macromolecular Drug CarriersR35GM138079 · NIGMS · TEXAS A&M UNIVERSITY · PI Quentin Nicolas Michaudel · 2020 to 2026
$2.2M
NIGMS NIH HHS R35 GM138079
6 · The paper itself

Abstract

Herein, we report a synthesis of medicinally relevant β-ketosulfonamides via a photomediated 1,3-rearrangement of alkenyl sulfamates. This protocol tolerates a wide array of sensitive functional groups including alkenes, alkynes, and nitrogen-based heterocycles. Additionally, this work provides a general approach toward alkenyl sulfamates via a two-step Sulfur(VI) Fluoride Exchange (SuFEx) sequence capitalizing on SO

Indexed as

Click ChemistryFluoridesMolecular StructureSulfonamidesSulfonic AcidsSulfurFluoridessulfamic acidSulfonamidesSulfonic AcidsSulfur

Identifiers

PMID34151557
PMCPMC8384055
OpenAlexW3173211809

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.